"Satoru Watanabe,Hiroaki Ozawa,Hiroaki Kato,Kaori Nimura-Matsune,Toshifumi Hirayama,Fumitaka Kudo,Tadashi Eguchi,Katsumi Kakinuma,Hirofumi Yoshikawa","Carbon-free Production of 2-Deoxy-scyllo-inosose (DOI) in Cyanobacterium Synechococcus elongatus PCC 7942",,"Biosci. Biotechnol. Biochem.",,"Vol. 82","No. 1","pp. 161-165",2018,Jan.
"Toshifumi Hirayama,Hideyuki Tamegai,Fumitaka Kudo,Kazumasa Kojima,Katsumi Kakinuma,Tadashi Eguchi","Biosynthesis of 2-Deoxystreptamine-containing Antibiotics in Streptoalloteichus hindudtanus JCM 3268: Characterization of 2-Deoxy-scyllo-inosose Synthase",,"J. Antibiot.",,"Vol. 59","No. 6","pp. 358-361",2006,June
"Fumitaka Kudo,Takashi Kitayama,Tadashi Eguchi,Katsumi Kakinuma","Macrolactam Formation Catalyzed by the Thioesterase Domain of Vicenistatin Polyketide Synthase",,"Tetrahedron Lett.",,"Vol. 47","No. 10","pp. 1529-1532",2006,Apr.
"Fumitaka Kudo,Yasuhito Yamamoto,Kenichi Yokoyama,Tadashi Eguchi,Katsumi Kakinuma","Biosynthesis of 2-Deoxystreptamine by Three Crucial Enzymes in Streptomyces fradiae NBRC12773",,"J. Antibiot.",,"Vol. 58","No. 12","pp. 766-774",2005,Dec.
"Fumitaka Kudo,Mario Numakura,Hideyuki Tamegai,Hideki Yamamoto,Tadashi Eguchi,Katsumi Kakinuma","Extended Sequence and Functional Analysis of the Butirosin Biosynthetic Gene Cluster in Bacillus circulans SANK 72073",,"J. Antibitot.",,"Vol. 58","No. 6","pp. 373-379",2005,June
"Kenichi Yokoyama,Fumitaka Kudo,Mieko Kuwahara,Kousuke Inomata,Hideyuki Tamegai,Tadashi Eguchi,Katsumi Kakinuma","Stereochemical Recognition of Doubly Functional Aminotransferase in 2-Deoxystreptamine Biosynthesis",,"J. Am. Chem. Soc.",,"Vol. 127","No. 16","pp. 5869-5874",2005,May
"Fumitaka Kudo,Kenichi Kawabe,Hisako Kuriki,Tadashi Eguchi,Katsumi Kakinuma","A New family of Pathways for Glucose-1-phosphate/Glucosamine-1-phosphate Nucleotidylyltransferase in the Biosynthetic Antibiotics",,"J. Am. Chem. Soc.",,"Vol. 127","No. 6","pp. 1711-1718",2005,Mar.
"E. Nango,T. Eguchi,K. Kakinuma","Active Site Mapping of 2-Deoxy-scyllo-inosose Synthase, the Key Starter Enzyme in the Biosynthesis of 2-Deoxystreptamine. Mechanism-based Inhibition and Identification of Lys-141 as an Entrapped Nucleophile",,"J. Org. Chem.",,"Vol. 69","No. 3","pp. 593-600",2004,
"S. Tohyama,T. Eguchi,R. P. Dhakal,T. Akashi,M. Otsuka,K. Kakinuma","Genome-Inspired Search for New Antibiotics. Isolation and Structure Determination of New 28-Membered Polyketide Macrolactones, Halstoctacosanolide A and B, from Streptomyces halstedii HC34",,"Tetrahedron",,"Vol. 60","No. 18","pp. 3999-4005",2004,
"Y. Ogasawara,K. Katayama,A. Minami,M. Otsuka,T. Eguchi,K. Kakinuma","Cloning, Sequencing, and Functional Analysis of the Biosynthetic Gene Cluster of Macrolactam Antibiotic Vicenistatin in Streptomyces halstedii",,"Chem. Biol.",,"Vol. 11","No. 1","pp. 79-86",2004,
"T. Eguchi,K. Yamamoto,K. Mizoue,K. Kakinuma","Structure Revision of FD-891, a 16-Membered Macrolide Antibiotic",,"J. Antibiot.",,"Vol. 57","No. 2","pp. 156-157",2004,
"Eriko Nango,Fumitaka Kudo,Tadashi Eguchi,Katsumi Kakinuma","Reaction Stereochemistry of 2-Deoxy-scyllo-inosose Synthase. The Key Enzyme in the Biosynthesis of 2-Deoxystreptamine-containing Aminoglycoside Antibiotics",,"Chem. Lett.",,"Vol. 32","No. 5","pp. 438-439",2003,May
"E. Nango,F. Kudo,T. Eguchi,K. Kakinuma","Reaction Stereochemistry of 2-Deoxy-scyllo-inosose Synthase. The Key Enzyme in the Biosynthesis of 2-Deoxystreptamine-containing Aminoglycoside Antibiotics",,"Chem. Lett.",,"Vol. 32","No. 5","pp. 438-439",2003,
"T. Yukita,H. Nishida,T. Eguchi. K. Kakinuma","Biosynthesis of (2R)-4-Amino-2-hydroxybutyric Acid, Unique and Biologically Significant Substituent in Butirosin",,"J. Antibiotics",,"Vol. 56","No. 5","pp. 497-500",2003,
"T. Eguchi,Y. Nishimura,K. Kakinuma","Importance of Isopropylidene Functionality of Di-O-Geranylgeranyl Glyserol for the Biosynthesis of Archaeal Macrocyclic Membrane Lipids",,"Tetrahedron Lett.",,"Vol. 44","No. 16","pp. 3275-3279",2003,
" T. Eguchi,Y. Dekishima,Y. Hamano,T. Dairi,H. Seto,K. Kakinuma","A New Approach for the Investigation of Isoprenoid Biosynthesis Featuring Pathway Switching, Deuterium Hyperlabeling and 1H NMR Spectroscopy. The Reaction Mechanism of a Novel Streptomyces Diterpene Cyclase",,"J. Org. Chem.",,"Vol. 68","No. 14","pp. 5433-5438",2003,
"T. Eguchi,E. Watanabe,K. Kakinuma","Practical Enantioselective Synthesis of Fully Deuterated (R)-Mevalonolactone",,"Tetrahedron",,"Vol. 59",,"pp. 6035-6038",2003,
"為我井秀行,柿沼勝己","「もの」が秘める可能性 ? アミノグリコシド抗生物質の生合成に学ぶ",,"化学と生物",,"Vol. 41","No. 11","pp. 763-771",2003,
"鈴木昭憲,荒井綜一,高木正道,室伏旭,磯部稔,柿沼勝己,他多数","農芸化学の事典",,"朝倉書店","朝倉書店",,,"pp. 295-300",2003,
"Hideyuki Tamegai,Eriko Nango,Ayumi Koike-Takeshita,Fumitaka Kudo,Katsumi Kakinuma","Significance of the 20 kDa Subunit of Heterodimeric 2-Deoxy-scyllo-inosose Synthase for the Biosynthesis of Butirosin Antibiotics in Bacillus circulans",,"Bioscience, Biotechnololgy, and Biochemistry",,"Vol. 66","No. 7","pp. 1538-1545",2002,July
"Y. Matsushima,H. Itoh,T. Nakayama,S. Horiuchi,T. Eguchi,K. Kakinuma","Enantioselective Total Synthesis of Vicenistatin, A Novel 20-Membered Macrocyclic Lactam Antitumor Antibiotic",,"Perkin 1",,"Vol. 2002","No. 7","pp. 949-958",2002,
"H. Tamegai,E. Nango,M. Kuwahara,H. Yamamoto,Y. Ota,H. Kuriki,T. Eguchi,K. Kakinuma","Identification of L-Glutamine:2-Deoxy-scyllo-inosose Aminotransferase Required for the Biosynthesis of Butirosin in Bacillus circulans",,"J. Antibiot.",,"Vol. 55","No. 8","pp. 707-714",2002,
"H. Tamegai,T. Eguchi,K. Kakinuma","First Identification of Streptomyces genes involved in the Biosynthesis of 2-Deoxy-streptamine-containing Aminoglycoside Antibiotics. Genetic and Evolutionary Analysis of L-Glutamine:2-Deoxy-scyllo-inosose Aminotransferase genes",,"J. Antibiot.",,"Vol. 55","No. 11","pp. 1016-1018",2002,
"T. Eguchi,K. Kobayashi,H. Uekusa,Y. Ohashi,K. Mizoue,Y. Matsushima,K. Kakinuma","Stereostructure of a Novel Cytotoxic 18-Membered Macrolactone Antibiotic FD-891",,"Org. Lett.",,"Vol. 4","No. 20","pp. 3383-3386",2002,
"T. Eguchi,S. Sasaki,Zhen Huang,K. Kakinuma","Importance of Specific Hydrogen-Bonding Donor-Acceptor Interactions for the Key Carbocycle-forming Reaction Catalyzed by 2-Deoxy-scyllo-inosose Synthase in the Biosynthesis of 2-Deoxystreptamine-containing Aminocyclitol Antibiotics",,"J. Org. Chem.",,"Vol. 67","No. 12","pp. 3979-3984",2002,
"H. Tamegai,E. Nango,A. Koike-Takeshita,F. Kudo,K. Kakinuma","Significance of the 20k-Da Subunit of Heterodimeric 2-Deoxy-scyllo-inosose Synthase for the Biosynthesis of Butirosin Antibiotics in Bacillus circulans",,"Biosci. Biotechnol. Biochem.",,"Vol. 66","No. 7","pp. 1538-1545",2002,
"H. Nishida,T. Eguchi,K. Kakinuma","Amino Acid Starter Unit in the Biosynthesis of Macrolactam Polyketide Antiumor Antibiotic Vicenistatin",,"Tetrahedron",,"Vol. 57",,"pp. 8237-8242",2001,
"M. Fujita,H. Tamegai,T. Eguchi,K. Kakinuma","Novel Substrate-Specificity of Designer 3-Isopropylmalate Dehydrogenase from Thermus thermophilus HB8",,"Biosci. Biotechnol. Biochem.",,"Vol. 65","No. 12","pp. 2695-2700",2001,
"K. Arakawa,T. Eguchi,K. Kakinuma","36-Membered Macrocyclic Diether Lipid is Advantageous for Archaea to Thrive under the Extreme Thermal Environments",,"Bull. Chem. Soc. Jpn",,"Vol. 74","No. 2","pp. 347-356",2001,
"K. Kakinuma,Y. Dekishima,Y. Matsushima,T. Eguchi,N. Misawa,M. Takagi,T. Kuzuyama,H. Seto","New Approach to Multiply Deuterated Isoprenoids Using Triply Engineered Escherichia coli and Its Potential for Mechanistic Enzymology",,"J. Am. Chem. Soc.",,"Vol. 123","No. 6","pp. 1238-1239",2001,
"Y. Matsushima,T. Nakayama,M. Fujita,R. Bhandari,T. Eguchi,K. Shindo,K. Kakinuma","Isolation and Structure Elucidation of Vicenistatin M, and Importance of the Vicenisamine Aminosugar for Exerting Cytotoxicity of Vicenistatin",,"J. Antibiot.",,"Vol. 54","No. 3","pp. 211-219",2001,
"Y. Matsushima,T. Nakayama,S. Toyama,T. Eguchi,K. Kakinuma","Versatile Route to 2,6-Dideoxyamino Sugars from Non-sugar Materials: Syntheses of Vicenisamine and Kedarosamine",,"J. Chem. Soc. Perkin Trans. I",,,"No. 6","pp. 569-577",2001,
"Y. Dekishima,T. Eguchi,K. Kakinuma,Y. Matsushima,N. Misawa,T. Kuzuyama,H. Seto","Preparation of Multiply Deuterated Carotenoids by Triply Engineered Escherichia coli with Perdeuterated Mevalonate",,"Carotenoid Science",,"Vol. 4","No. 1","pp. 64-65",2001,
"K. Arakawa,T. Eguchi,K. Kakinuma","Highly Thermostable Liposome from 72-Membered Macrocyclic Tetraether Lipid: Importance of 72-Membered Lipid for Archaea to Thrinve under Hyperthermal Environments",,"Chem. Lett.",,,"No. 5","pp. 440-441",2001,
"S. Sakuda,Y. Sugiyama,Z.-Y. Zhou,H. Takao,H. Ikeda,K. Kakinuma,Y. Yamada,H. Nagasawa","Biosynthetic Studies on the Cyclopentane Ring Formation of Allosamizoline, an Aminocyclitol Component of the Chitinase Inhibitor Allosamidin",,"J. Org. Chem.",,"Vol. 66","No. 10","pp. 3356-3361",2001,
"Yasumasa Ota,Hideyuki Tamegai,Fumitaka Kudo,Hisako Kuriki,Aumi Koike-Takeshita,Tadashi Eguchi,Katsumi Kakinuma","Butirosin-biosynthetic Gene Cluster from Bacillus circulans",,"J. Antibiot.",,"Vol. 53","No. 10","pp. 1158-1167",2000,Oct.
"Katsumi Kakinuma,Eriko Nango,Fumitaka Kudo,Yoshitaka Matsushima,Tadashi Eguchi","An Expeditious Chemo-enzymatic Route from Glucose to Catechol by the Use of 2-Deoxy-scyllo-inosose Synthase",,"Tetrahedron Letters",,"Vol. 41","No. 12","pp. 1935-1938",2000,Apr.
"K. Kakinuma,E. Nango,F. Kudo,Y. Matsushima,T. Eguchi","An Expeditious Chemo-Enzymatic Route from Glucose to Catechol by the Use of 2-Deoxy-scyllo-inosose Synthase",,"Tetrahedron Lett.",,"Vol. 41","No. 12","pp. 1935-1938",2000,
"M. Otsuka,M. Fujita,Y. Matsushima,T. Eguchi,K. Shindo,K. Kakinuma","Biosynthetic Pathway of Macrolactam Polyketide Glycoside Antitumor Antibiotic Vicenistatins.",,"Tetrahedron",,"Vol. 56","No. 42","pp. 8281-8286",2000,
"Y. Ota,H. Tamegai,F. Kudo,H. Kuriki,A. Koike-Takeshita,T. Eguchi,K. Kakinuma","Butirosin Biosynthetic Gene Cluster from Bacillus circulans",,"J. Antibiot.",,"Vol. 53","No. 10","pp. 1158-1167",2000,
"T. Eguchi,K. Arakawa,K. Kakinuma,G. Rapp,S. Ghosh,Y. Nakatani,G. Ourisson","Giant Vesicles from 72-Membered Macrocyclic Archaeal Phospholipid Analogues. Initiation of Vesicle Formation by Molecular Recognition between Membrane Components",,"Chem. Eur. J. ",,"Vol. 6","No. 18","pp. 3351-3358",2000,
"柿沼勝己","バイオマスを化学資源に ?二次代謝酵素の可能性?",,"バイオサイエンスとインダストリー",,"Vol. 58","No. 12","pp. 39-40",2000,
"O. Dannenmuller,K. Arakawa,T. Eguchi,K. Kakinuma,S. Blanc,A.-M. Albrecht,M. Schmutz,Y. Nakatani,G. Ourisson","Membrane Properties of Archaeal Macrocyclic Diether Phospholipids",,"Chem., Eur. J.",,"Vol. 6","No. 4","pp. 645-654",2000,
"M. Fujita,Y. Toyooka,H. Tamegai,T. Eguchi,K. Kakinuma","Arg-94 is crucial to the catalysis of 3-isopropylmalate dehydrogenase from Thermus thermophilus HB8",,"J. Mol. Cat. B: Enzymatic.",,"Vol. 9",,"pp. 149-155",2000,
"T. Eguchi,S. Kanai,K. Kakinuma,T. Okazaki,K. Mizoue","Synthesis of NG-061 and Its Analogs, and Their Biological Evaluation as an Enhancer of Nerve Growth Factor",,"Chem. Pharm. Bull.",,"Vol. 48","No. 10","pp. 1470-1473",2000,
"T. Eguchi,H. Takyo,M. Morita,K. Kakinuma,Y. Koga;","Unusual Double-Bond Migration as Plausible Key Reaction in the Biosynthesis of the Isoprenoidal Membrane Lipids of Methanogenic Archae",,"Chem. Commun.",,,"No. 16","pp. 1545-1546",2000,
"Fumitaka Kudo,Yoshihiro Hosomi,Hideyuki Tamegai,Katsumi Kakinuma","Purification and Characterization of 2-Deoxy-scyllo-inosose Synthase Derived from Bacillus circulans. A Crucial Carbocyclization Enzyme in the Biosynthesis of 2-Deoxystreptamine-containing Aminoglycoside Antibiotics",,"Journal of Antibiotics",,"Vol. 52","No. 2","pp. 81",1999,Feb.
"A. Chiba,N. Arai,T. Eguchi,K. Kakinuma","3-Isopropylidenemalic Acid : A Mechanism-based Inhibitor of 3-Isopropylmalate Dehydrogenase",,"Chem. Lett.",,,"No. 12","pp. 1313-1314",1999,
"127) A. Chiba,T. Aoyama,R. Suzuki,T. Eguchi,T. Oshima,K. Kakinuma","Synthetic and Mechanistic Studies of (2R,3S)-3-Vinylmalic Acid as A Mechanism-based Inhibitor of 3-Isopropylmalate Dehydrogenase",,"J. Org. Chem.",,"Vol. 64","No. 17","pp. 6159-6165",1999,
"F. Kudo,Y. Hosomi,H. Tamegai,K. Kakinuma","Purification and Characterization of 2-Deoxy-scyllo-inosose Synthase Derived from Bacillus circulans. A Crucial Carbocyclization Enzyme in the Biosynthesis of 2-Deoxystreptamine-containing Aminoglycoside Antibiotics",,"J. Antibiot.",,"Vol. 52","No. 2","pp. 81-88",1999,
"129) M. Ito,N. Sakai,K. Ito,F. Mizobe,K. Hanada,K. Mizoue,R. Bhandari,T. Eguchi,K. Kakinuma","A Novel Fungal Metabolite NG-061 Enhances and Mimics Neurotrophic Effect of Nerve Growth Factor (NGF) on Neurite Outgrowth in PC12 Cells",,"J. Antibiot.",,"Vol. 52","No. 3","pp. 224-230",1999,
"R. Bhandari,T. Eguchi,A. Sekine,Y. Ohashi, K,Kakinuma","Structure, of NG-061, A Novel Potentiator of Nerve Growth Factor (NGF) Isolated from Penicillium miniolutem F-4647",,"J. Antibiot., 52 [3], 231-234 (1999)",,"Vol. 52","No. 3","pp. 231-234",1999,
"F. Kudo,H. Tamegai,T. Fujiwara,U. Tagami,K. Hirayama,K. Kakinuma","Molecular Cloning of the Gene for the Key Carbocycle-forming Enzyme in the Biosynthesis of 2-Deoxystreptamine-containing Aminocyclitol Antibiotics and Its Comparison with Dehydroquinate Synthase",,"J. Antibiot.",,"Vol. 52","No. 6","pp. 559-571",1999,
"A. Chiba,T. Eguchi,T. Oshima,K. Kakinuma","Synthesis of Cyclopropane Substrate Analog for 3-Isopropylmalate Dehydrogenase and Its Mechanism-Based Inhibition",,"Tetrahedron",,"Vol. 55",,"pp. 2927-2936",1999,
"K. Arakawa,H. Kano,T. Eguchi,Y. Nishiyama,K. Kakinuma","Significance of the 72-Membered Macrocyclic Structure Found in Archaeal Membrane Lipids: Model Studies the Macrocyclic Tetraether Diphospholipids by Calorimetric, 31P-NMR, and Electron Microscopic Analyses",,"Bull. Chem. Soc. Jpn.",,"Vol. 72","No. 7","pp. 1575-1581",1999,
"A. Chiba,T. Eguchi,T. Oshima,K. Kakinuma","Coenzyme Activity of NAD Analogs for 3-Isopropylmalate Dehydrogenase from Thermus thermophilus HB8",,"Biosci. Biotechnol. Biochem.",,"Vol. 63","No. 9","pp. 1647-1649",1999,
"O. Dannenmuller,K. Arakawa,T. Eguchi,K. Kakinuma,S. Blanc,A.-M. Albrecht,Y. Nakatani,G. Ourisson","Membrane Properties of Archaeal Phospholipids : Effect of Macrocyclization",,"Giant Vesicles, John Wiley & Sons Ltd.","Giant Vesicles, John Wiley & Sons Ltd.",,,"pp. 385-390",1999,
"柿沼勝己","生合成研究における有機合成の重要性",,"ファルマシア",,"Vol. 35","No. 7","pp. 700-705",1999,
"江口正,荒川賢治,柿沼勝己","３０員環を越す巨大な環状化合物の合成：古細菌細胞膜の脂質分子を中心として",,"有機合成化学協会誌",,"Vol. 57","No. 9","pp. 784-797",1999,
"T. Eguchi,K. Kondo,K. Kakinuma,H. Uekusa,Y. Ohashi,K. Mizoue,Y.-F. Qiao","Unique Solvent-dependent Atropisomerism of A Novel Cytotoxic Naphthoxanthene Antibiotic FD-594",,"J. Org. Chem.",,"Vol. 64","No. 15","pp. 5371-5376",1999,
"Noriaki Iwase,Fumitaka Kudo,Noriaki Yamauchi,Katsumi Kakinuma","Biochemical Studies on 2-Deoxy-scyllo-inosose, an Early Intermediate in the Biosynthesis of 2-Deoxystreptamine. VII. Substrate Specificity of 2-Deoxy-scyllo-inosose Synthase, the Starter Enzyme for 2-Deoxystreptamine Biosynthesis, toward Deoxyglucose-6-phosphates and Proposed Mechanism",,"Bioscience, Biotechnology, and Biochemistry",,"Vol. 62","No. 12","pp. 2396-2407",1998,Dec.
"T. Eguchi,M. Fukuda,Y. Toyooka,K. Kakinuma","Rational De Novo Design of NADH Mimic for Stereoselective Reduction Based on Molecular Orbital Calculation",,"Tetrahedron",,"Vol. 54",,"pp. 705-714",1998,
"K. Kakinuma,T. Eguchi","Chirality Transfer on Carbohydrate Template : A Versatile Approach for Chiral Deuterium Labeling",,"Synthesis and Applications of Isotopically Labelled Compounds 1997","Synthesis and Applications of Isotopically Labelled Compounds 1997",,,"pp. 543-546",1998,
"H. Morii,T. Eguchi,M. Nishihara,K Kakinuma,H. Konig,Y. Koga","A Novel Ether Core Lipid with an H-Shaped C┣D280┫D2-Isoprenoid Hydrocarbon Chain from the Hyperthermophilic Methanogen Methanothermus fervidus",,"Biochim. Biophys. Acta",,"Vol. 1390","No. 3","pp. 339-345",1998,
"KATSUMI KAKINUMA","Overproduction and Substrate Specificity of 3-Isopropylmalate Dehydrogenase from Thiobacillus ferrooxidans",,"Biosci. Biotechnol. Biochem.",,"Vol. 62","No. 2","pp. 372-373",1998,
"KATSUMI KAKINUMA","Structural Diversity of Membrane Core Lipid of Extreme Halophile",,"Biosci. Biotechnol. Biochem.",,"Vol. 62","No. 3","pp. 596-598",1998,
"T. Eguchi,M. Morita,K. Kakinuma","Multi-gram Synthesis of Mevalonolactone-d┣D29┫D2 and Its Application to the Stereo-chemical Analysis of Saturation Reaction in the Biosynthesis of 2,3-Di-O-phytanyl-sn-glycerol Core of Archaeal Membrane Lipid as Studied by ┣D11┫D1H-NMR",,"J. Am. Chem. Soc.",,"Vol. 120","No. 22","pp. 5427-5433",1998,
"T. Eguchi,K. Ibaragi,K. Kakinuma","Total Synthesis of Archaeal 72-Membered Macrocyclic Tetraether Lipids",,"J. Org. Chem.",,"Vol. 63","No. 8","pp. 2689-2698",1998,
"KATSUMI KAKINUMA","Isolation and Characterization of A New Pyrano[4', 3' : 6,7]naphtho[1,2-b]xanthene Antibiotic FD-594",,"J. Antibiot.",,"Vol. 51","No. 3","pp. 282-287",1998,
"K. Kondo,T. Eguchi,K. Kakinuma,K. Mizoue,Y.-F. Qiao","Structure and Biosynthesis of FD-594 ; A New Antitumor Antibiotic",,"J. Antibiot.",,"Vol. 51","No. 3","pp. 288-295",1998,
"KATSUMI KAKINUMA","Absolute Stereochemistry of Vicenistatin, A Novel 20-Membered Macrocyclic Lactam Antitumor Antibiotic",,"Tetrahedron Lett.",,"Vol. 39","No. 20","pp. 3181-3184",1998,
"M. Otsuka,T. Eguchi,K. Shindo,K. Kakinuma","Non-Fatty Acyl Polyketide Starter in the Biosynthesis of Vicenistatin, an Antitumor Macrolactam Antibiotic",,"Tetrahedron Lett.",,"Vol. 39","No. 20","pp. 3185-3188",1998,
"KATSUMI KAKINUMA","Enantioselective and Convergent Synthesis of the 20-Membered Lactam Aglycon of Vicenistatin Antitumor Antibiotic",,"J. Antibiot.",,"Vol. 51","No. 7","pp. 688-691",1998,
"KATSUMI KAKINUMA","Solvent-dependent Stereochemical Anomaly in the Nucleophilic Addition of Ester-derived Enolate to Bicyclo[3,3,0]octan-2-one System of Diacetone glucos-3-ulose",,"Chem. Lett.",,"Vol. 1998","No. 6","pp. 475-476",1998,
"KATSUMI KAKINUMA","An Olefin Metathesis Approach to 36-and 72-Membered Archaeal Macrocyclic Membrane Lipids",,"J. Org. Chem.",,"Vol. 63","No. 14","pp. 4741-4745",1998,
"KATSUMI KAKINUMA","Tightly Packed Membranes Composed of 36-Membered Macrocyclic Diether Phospholipids Found in Archae Growing under Deep-Sea Hydrothermal Vents",,"Chem. Lett.",,"Vol. 1998","No. 9","pp. 901-902",1998,
"KATSUMI KAKINUMA","Substrate Specificity of 2-Deoxy-scyllo-inosose Synthase, the Starter Enzyme in 2-Deoxystreptamine Biosynthesis, toward Deoxyglucose-6-phosphates and Proposed Mechanism",,"Biosci. Biotechnol. Biochem.",,,,"pp. 62",1998,
"KATSUMI KAKINUMA","Specific Deuterium Labeling of Archaeal 36-Membered Macrocyclic Diether Lipid",,"Bull. Chem. Soc. Jpn",,,,"pp. 71",1998,
"KATSUMI KAKINUMA","Biosynthesis of Riboflavin. Stereochemistry of the 3,4-Dihydroxy-2-butanone 4-phosphate Synthase Reaction",,"J. Org. Chem.",,,,"pp. 63",1998,
"F. Kudo,N. Yamauchi,R. Suzuki,K. Kakinuma","Kinetic Isotope Effect and Reaction Mechanism of 2-Deoxy-scyllo-inosose Synthase Derived from Butirosin-producing Bacillus circulans",,"J. Antibiot.",,"Vol. 50","No. 5","pp. 424-429",1997,
"KATSUMI KAKINUMA","Diacetone-glucose Architechture as a Chirality Template. Part9. Enantioselective Synthesis of (R)-Mevalolactone and (R)-[┣D12┫D1H┣D29┫D2]Mevalolactone on Carbohydrate Template.",,"J. Chem. Soc. Perkin I",,,,"pp. 891-895",1997,
"KATSUMI KAKINUMA","Total Synthesis of Archaeal 36-Membered Macrocyclic Diether Lipid",,"J. Org. Chem. ,",,"Vol. 36","No. 7","pp. 1924-1933",1997,
"KATSUMI KAKINUMA","Synthesis of Conformationally Restricted Substrate Analogs and Their Interaction with 3-Isopropylmalate Dehydrogenase Derived from Thermophile Thermus thermophilus",,"Tetrahedron",,"Vol. 53","No. 10","pp. 3537-3544",1997,
"KATSUMI KAKINUMA","Synthetic Studies of Archaeal Macrocyclic Tetraether Lipids : Practical Synthesis of 72-Membered Tetraether Model Compounds",,"Bull. Chem. Soc. Jpn",,"Vol. 70","No. 10","pp. 2545-2554",1997,
"KATSUMI KAKINUMA","Mechanistic Enzymology and Molecular Recognition of 3-Isopropylmalate Dehydrogenase Derived from an Extreme Thermophile Thermus thermophilus HB8",,"KODANSHA : Dynamic Aspects of Natural Products Chemistry","KODANSHA : Dynamic Aspects of Natural Products Chemistry",,,"pp. 187-208",1997,
"KATSUMI KAKINUMA","A Versatile Synthon for Chirelly β-Deuterated L-Amino Acids and Synthesis of (3R)-and(3S)-[3-┣D12┫D1H┣D21┫D2]-L-Serine",,"Biosci.Biotech.Biochem.,",,"Vol. 60","No. 7",,1996,
"KATSUMI KAKINUMA","Remote Asymmetric Induction Observed in the Alkylation of Propionate Attached to Carbohydrate Template",,"Terahedron Lett.,",,"Vol. 37","No. 12","pp. 2061-2062",1996,
"KATSUMI KAKINUMA","The First Synthesis of 72-Membered Macrocyclic Model Lipids Desmethylated Analogues to Membrane Lipids of Archaefacteria Growing in Etreme Environments",,"J.Chem.Soc.Chem.Commun",,,,"pp. 365-366",1996,
"KATSUMI KAKINUMA","NADH Mimics on Diacetone-D-Glucose : Stereoselective Biomimetic Reduction of Benzoylformate and Interpretation of Chirality Transfer Deduced by Molecular Orbital Approach",,"Tetrahedron",,"Vol. 51","No. 23","pp. 6459-6474",1995,
"KATSUMI KAKINUMA","Synthesis of DL-threo-3-(1-Fluoro-1-methylethyl)-and DL-threo-3-(1,1-Difluoroethyl)malic Acids. Mechanistic Studies of 3-Isopropylmalate Dehydrogenase",,"J. Chem. Soc. Perkin I",,,"No. 17","pp. 1905-1912",1995,
"KATSUMI KAKINUMA","Enzymatic Carbocycle Formation in Microbial Secondary Metabolism. The Mechanism of 2-Deoxy-scyllo-inosose Synthase Reaction As a Crucial Step of the 2-Deoxystreptamine Biosynthesis in Streptomyces fradiae",,"J. Org. Chem.",,"Vol. 60","No. 37","pp. 5614-5619",1995,
"R. K. Mukherjee,Y. Fujimoto,K. Kakinuma","(1-ω-Hydroxyfattyacyl)glycerols and two flavanols from Cinnamomum camphora",,"Phytochemistry",,"Vol. 37","No. 6","pp. 1641-1643",1994,Dec.
"M. Nagakari,T. Kushiro,T. Matsumoto,N. Tanaka,K. Kakinuma,Y. Fujimoto","Incorporation of acetate and cholesterol into 20-hydroxyecdysone by hairy root clone of Ajuga reptans var. atropurpurea",,"Phytochemistry",,"Vol. 36","No. 4","pp. 907-910",1994,July
"Y. Fujimoto,C. Murasaki,T. Eguchi,K. Kakinuma,C. P. Dutta","Formation of 9,25-cyclofernane by reductive homoallylic cyclization of fern-9(11)-en-25-ol mesylate",,"Chem. Pharm. Bull.",,"Vol. 42","No. 6","pp. 1334-1335",1994,June
"Y. Fujimoto,C. Murasaki,H. Shimada,S. Nishioka,K. Kakinuma,S. Singh, M.,Singh,Y. K. Gupta,M. Sahai","Annonaceous acetogenins from the seeds of Annona squamosa. Non-adjacent bis-tetrahydrofuranic acetogenins",,"Chem. Pharm. Bull.",,"Vol. 42","No. 6","pp. 1175-1184",1994,June
"M. Sahai,M. Singh,Y. K. Gupta,S. Akashi,R. Yuji,K. Hirayama,H. Asaki,H. Araya,N. Hara,T. Eguchi,K. Kakinuma,Y. Fujimoto","Annonaceous acetogenins from the seeds of Annona squamosa. Adjacent bis-tetrahydrofuranic acetogenins",,"Chem. Pharm. Bull.",,"Vol. 42","No. 6","pp. 1163-1174",1994,June
"KATSUMI KAKINUMA","Synthesis of 2-O-Methyl Ether and 1-Corboxamide Derivatives of (2R,3R)-3-Isopropylmalic Acid and Their Interaction with Thermoplilic 3-Isopropylmalate Dehydrogenase",,"Biosci.Biotech.Biochem.,",,"Vol. 58","No. 8","pp. 870-873",1994,
"KATSUMI KAKINUMA","Mechamistic and Stereochmical Studies on Ferrier Reaction by Meano of Chirally Deuterated Glucose",,"Tetrahedron",,"Vol. 50","No. 14","pp. 4125-4136",1994,
"KATSUMI KAKINUMA","Crystal Structure of Ethyl(2S┣D1*┫D1, 3R┣D1*┫D1)-2-Benzoyloxy-4,4-difluoro-3-(4-methoxyphenyl)-pentanoate",,"Analytical Sci.,",,"Vol. 10",,"pp. 519-520",1994,
"KATSUMI KAKINUMA","Formation of 9,25-Cyclofernane by Reductive Homoallylic Cyclization of Fern-9(11)-en-25-ol Mesylate",,"Chem. Pharm. Bull.",,"Vol. 42","No. 6","pp. 1334-1335",1994,
"KATSUMI KAKINUMA","(1-ω-Hydroxyfattyacyl)glycerols and Two Flavanols from Cinnamomum camphora",,"Phytochemistry",,"Vol. 37","No. 6","pp. 1641-1643",1994,
"KATSUMI KAKINUMA","3β-Hydroxy-5β-cholest-7-en-6-one as an Intermediate of 20-Hydroxyecdysone Biosynthesis in Hairy Root Culture of Ajuga reptans var. atropurpurea",,"J. Chem. Soc. Chem. Commun.",,"Vol. 15",,"pp. 1761-1762",1994,
"KATSUMI KAKINUMA","Annonaceous Acetogenins from the Seeds of Annona squamosa. Non-adjacent Bistetrahedrofuranic Acetogenins",,"Chem. Pharm. Bull.",,"Vol. 42","No. 6","pp. 1175-1184",1994,
"KATSUMI KAKINUMA","Synthesis of 2-O-Methyl Ether and 1-Carboxamide Derivatives of (2R, 3S)-3-Isopropylmalic Acid and Their Interaction with Thermophilic 3-Isopropylmalate Dehydrogenase",,"Biosci. Biotech. Biochem.",,"Vol. 58","No. 8","pp. 870-873",1994,
"KATSUMI KAKINUMA","Mechanistic and Stereochemical Studies on Ferrier Reaction by Means of Chirally Deuterated Glucose",,"Tetrahedron",,"Vol. 50","No. 14","pp. 4125-4136",1994,
"KATSUMI KAKINUMA","Incorporation of Acetate and Chlosterol into 20-Hydroxyecdysone with Hairy Root Clone of Ajuga reptans var. atropurpurea",,"Phytochemistry",,"Vol. 36","No. 4","pp. 907-910",1994,
"KATSUMI KAKINUMA","Annonaceous Acetogenins from the Seeds of Annona squamosa. Adjacent Bis-tetrahedro-furanic Acetogenins",,"Chem. Pharm. Bull.",,"Vol. 42","No. 6","pp. 1163-1174",1994,
"KATSUMI KAKINUMA","Annonaceous Acetogenins from the Seeds of Annona squamosa. Nonadjacent Bis-tetrahedrofuranic Acetogenins",,"Chem. Pharm. Bull.",,"Vol. 42","No. 6","pp. 1157-1184",1994,
"M. Nagakari,T. Kushiro,T. Yagi,T. Matsumoto,N. Tanaka,K. Kakinuma,Y. Fujimoto","3β-Hydroxy-5β-cholest-7-en-6-one as an intermediate of 20-hydroxyecdysone biosynthesis in a hairy root culture of Ajuga reptans var. atropurpurea",,"J. Chem. Soc., Chem. Commun.",,,"No. 15","pp. 1761-1762",1994,
"C. P. Dutta,J. Banerjee,G. Datta,U. K. Som,T. Eguchi,C. Murasaki,K. Kakinuma,Y. Fujimoto","Tuberosic acid, a pentacyclic triterpene from Nephrolepsis tuberosa",,"Phytochemistry",,"Vol. 33","No. 1","pp. 240-242",1993,Apr.
"J. Mungarulire,R. M. Munabu,C. Murasaki,T. Eguchi,Y. Fujimoto,K. Kakinuma,K. Kobayashi,M. Uramoto,N. Ikekawa","A novel steroidal saponin, pogosterol from Vernonia pogosperma",,"Chem. Pharm. Bull.",,"Vol. 41","No. 2","pp. 411-413",1993,Feb.
"KATSUMI KAKINUMA","Enantioselective Synthesis of (2R, 3S)-3-Alkylmalic Acids, Competent Substrates of 3-Isopropylmalate Dehydrogenase",,"Biosci. Biotech. Biochem.",,"Vol. 57","No. 11","pp. 1916-1923",1993,
"KATSUMI KAKINUMA","A Novel Steroidal Sapogenin, Pogosterol from Vernonia pogosperma",,"Chem. Pharm. Bull.",,"Vol. 41","No. 2","pp. 411-413",1993,
"KATSUMI KAKINUMA","The Overman Rearrangement on a Diacetone-D-Glucose Template : Kinetic and Theoretical Studies on the Chirality Transcription",,"Tetrahedron",,"Vol. 49","No. 21","pp. 4527-4540",1993,
"KATSUMI KAKINUMA","Direct Closure of a 36-Membered Ring Using the McMurry Couplin : Synthetic Studies on the Macrocyclic Archaebacterial Membrane Lipids",,"Tetrahedron Lett.",,"Vol. 34","No. 13","pp. 2175-2178",1993,
"KATSUMI KAKINUMA","Chemical Transformation of Gilvocarcin V. Modification of the Side-chain",,"J. Antibiot.",,"Vol. 46","No. 6","pp. 985-991",1993,
"KATSUMI KAKINUMA","Tuberosic Acid, A Pentacyclic Triterpene from Nephrolepsis tuberosa",,"Phytochemistry",,"Vol. 33","No. 1","pp. 240-242",1993,
"KATSUMI KAKINUMA","An Alkalophilic Bacillus Produces 2-Phenylethylamine",,"Appl. Environ. Microbiol.",,"Vol. 59","No. 8","pp. 2720-2722",1993,
"KATSUMI KAKINUMA","Kinetic Analysis on the Substrate Specificity of 3-Isopropylmalate Dehydrogenase",,"FEBS Lett.",,"Vol. 332","No. 1-2","pp. 35-36",1993,
"KATSUMI KAKINUMA","Biochemical Studies on 2-Deoxy-scyllo-inosose, An Early Intermediate in the Biosynthesis of 2-Deoxystreptamine. IV. A Clue to the Mechanistic Similarity of 2-deoxy-scyllo-inosose Synthase in the 2-Deoxystreptamine Biosynthesis to Dehydroquinate Synthase",,"J. Antibiot.",,"Vol. 46","No. 12","pp. 1916-1918",1993,
"KATSUMI KAKINUMA","Confirmation of In Vitro Synthesis of 2-Deoxy-scyllo-inosose, the Earliest Intermediate in the Biosynthesis of 2-Deoxystreptamine, Using Cell-Free Preparation of Streptomyces fradiae",,"J. Antibiot.",,"Vol. 45","No. 5","pp. 774-780",1992,
"KATSUMI KAKINUMA","The Fate of the Hydrogens of D-Glucose during the Lipid Biosynthesis and Stereochemistry of the Triose-phosphate Isomerase Reaction in Archaebacteria Halobacterium halobium",,"Tetrahedron Lett.",,"Vol. 33","No. 43","pp. 6479-6482",1992,
"KATSUMI KAKINUMA","Remarkable Reversal of Stereoselectivity in Wittig-Type Olefinations of a-Fluorinated Alkyl Aryl Ketones",,"Tetrahedron Lett.",,"Vol. 33","No. 38","pp. 5545-5546",1992,
"KATSUMI KAKINUMA","Confirmation of ┣DBIn Vitro(/)-┫DB Synthesis of 2-Deoxy-┣DBScyllo(/)-┫DB-inosose, the Earliest Intermediate in the Biosynthesis of 2-Deoxystreptamine Using Cell-Free Preparation of ┣DBStreptomycesfradiae(/)-┫DB",,"Journal of Antibiotics",,"Vol. 45",,"pp. 5",1992,
"KATSUMI KAKINUMA","Diacetone Glucose Architecture as a Chirality Template. II. Versatile Synthon for the Chiral Deuterium Labeling and Synthesis of All Diastereoisomers of Chirally Monodeuterated Glycerol",,"Tetrahedron",,"Vol. 48","No. 18","pp. 3763-3774",1992,
"KATSUMI KAKINUMA","Biochemical Studies on 2-Deoxy-scyllo-inosose, An Early Intermediate in the Biosynthesis of 2-Deoxystreptamine. I. Chemical Synthesis of 2-Deoxy-scyllo-inosose and [2,2-┣D12┫D1H┣D22┫D2]-2-Deoxy-scyllo-inosose",,"J. Antibiot.",,"Vol. 45","No. 5","pp. 756-766",1992,
"KATSUMI KAKINUMA","Biochemical Studies on 2-Deoxy-scyllo-inosose, An Early Intermediate in the Biosynthesis of 2-Deoxystreptamine. II. Quantitative Analysis of 2-Deoxy-scyllo-inosose",,"J. Antibiot.",,"Vol. 45","No. 5","pp. 767-773",1992,
"KATSUMI KAKINUMA","Enantiocontrol by Intrinsic Antiparallel Double Repulsion on Diacetone-D-Glucose Template. Enantioselective Synthesis of Alanine and Chirally Deuterated Glycine",,"Tetrahedron Letters",,"Vol. 32",,"pp. 41",1991,
"KATSUMI KAKINUMA","Synthesis of [19-┣D113┫D1C]-1α-Hydroxyvitamin D┣D23┫D2 and ┣D113┫D1C-NMR Analysis of the Conformational Equilibrium of the A-ring",,"Bioorganic. Chem.",,"Vol. 19",,"pp. 327-332",1991,
"KATSUMI KAKINUMA","Fern-9(11)-en-25-oic Acid, A Triterpene from Adiantum venustum",,"Phytochemistry",,"Vol. 30","No. 10","pp. 3478-3480",1991,
"KATSUMI KAKINUMA","Diacetone Glucose Architecture as a Chirality Template I. Crucial Effects of the Intramolecular Oxygens upon the LiAlH┣D24┫D2 Reduction on the Propargyl Alcohol of 3-C-Ethynyl 1,2- : 5,6-di-O-Isopropylidene-α-D-Allofuranose Derivatives",,"Tetrahedron",,"Vol. 47","No. 34","pp. 6975-6982",1991,
"Y. Fujimoto,M. Nagakari,Y. Ikuina,N. Ikekawa,K. Kakinuma","Stereochemistry of the hydrogen addition to C-25 of desmosterol by sterol-Δ24-reductase of the silkworm, Bombyx mori",,"J. Chem. Soc., Chem. Commun.",,,"No. 10","pp. 688-689",1991,
"J. Banerjee,G. Datta,C. P. Dutta,T. Eguchi,Y. Fujimoto,K. Kakinuma","Fern-9(11)-en-25-oic acid, a triterpene from Adiantum venustum",,"Phytochemistry",,"Vol. 30","No. 10","pp. 3478-3480",1991,
"Y. Fujimoto,T. Eguchi,C. Murasaki,Y. Ohashi,K. Kakinuma,H. Takagaki,M. Abe,K. Inazawa,K. Yamazaki,N. Ikekawa,O. Yoshikawa,T. Ikekawa","Studies on the structure and stereochemistry of cytotoxic furanonaphthoquinones from Tabebuia impetiginosa: 5- and 8-hydroxy-2-(1-hydroxyethyl)naphtho[2,3-b]furan-4,9-diones",,"J. Chem. Soc., Perkin Trans. 1",,,"No. 10","pp. 2323-2327",1991,
"K. Kakinuma,M. Yamagishi,Y. Fujimoto,N. Ikekawa,T. Oshima","Biosynthetic mechanism of sn-2,3-di-O-phytanylglycerol, core membrane lipid of the Archaebacterium Halobacterium halobium",,"J. Am. Chem. Soc.",,"Vol. 112","No. 7","pp. 2740-2745",1990,Mar.
"Y. Fujimoto,Y. Ikuina,Y. Kanzawa,M. Nagakari,K. Kakinuma,N. Ikekawa","Mechanism of BF3・etherate-catalyzed rearrangement of fucosterol epoxide",,"Heterocycles",,"Vol. 30","No. 1","pp. 275-278",1990,Jan.
"KATSUMI KAKINUMA","Biosynthetic Mechanism of ┣DBsn(/)-┫DB-2,3-Di-O-Phytanyl Glycerol, Core Membrane Lipid of the Archaebacterium ┣DBHalobacterium(/)-┫DB ┣DBhalobium(/)-┫DB",,"Journal of the American Chemical Society",,"Vol. 112",,"pp. 7",1990,
"Y. Fujimoto,C. Murasaki,K. Kakinuma,T. Eguchi,N. Ikekawa,M. Furuya,K. Hirayama,T. Ikekawa,M. Sahai,Y. K. Gupta,A. B. Ray","Squamostatin-A: Unprecedented bis-tetrahydrofuran acetogenin from Annona squamosa",,"Tetrahedron Lett.",,"Vol. 31","No. 4","pp. 535-538",1990,
"Y. Fujimoto,K. Kakinuma,T. Eguchi,N. Ikekawa,N. Hirayama,A. Mbarushimana,D. Ntahomvukiye","12,15-Dihydroxylabda-8(17),13-dien-19-oic acid from Guizotia scabra",,"Phytochemistry",,"Vol. 29","No. 1","pp. 319-321",1990,
"Y. Fujimoto,Y. Ikuina,M. Nagakari,K. Kakinuma,N. Ikekawa","C-25 Prochirality in the fragmentation reaction catalyzed by fucosterol epoxide lyase from the silkworm, Bombyx mori",,"J. Chem. Soc., Perkin Trans. 1",,,"No. 7","pp. 2041-2046",1990,
"Y. Ikuina,Y. Kanzawa,Y. Fujimoto,K. Kakinuma","Preparation of (26-13C) desmosterol",,"Chem. Pharm. Bull.",,"Vol. 37","No. 7","pp. 1755-1757",1989,July
"Y. Fujimoto,M. Hiramoto,K. Kakinuma,N. Ikekawa","Elimination of C-6-hydrogen during the formation of ecdysteroids from cholesterol in Locusta migratoria ovaries",,"Steroids",,"Vol. 53","No. 3-5","pp. 477-485",1989,Mar.
"KATSUMI KAKINUMA","Stereochemistry of Decarboxylation Catalyzed by3-Isopropylmalete Dehydrogenase from The Thermophilic Bacteria ┣DBThermus Thermophilus(/)-┫DB",,"Journal of the Chemical Society, Chmical Communication",,,,"pp. 17",1989,
"KATSUMI KAKINUMA","Mechanism and Stereochemistry of the Biosynthesis of 2-Deoxystreptamine and Neosamine C",,"Journal of Antibiotics",,"Vol. 42",,"pp. 6",1989,
"KATSUMI KAKINUMA","[2,3]-Wittig Rearrangement of Carbohydrate Template. Novel Approach to Chiral Synthesis of 3-Alkylmalic Acids",,"Tetrahedron Letters",,"Vol. 30",,"pp. 31",1989,
"E. Ohnishi,M. Hiramoto,Y. Fujimoto,K. Kakinuma,N. Ikekawa","Isolation and identification of major ecdysteroid conjugates from the ovaries of Bombyx mori",,"Insect Biochemistry",,"Vol. 19","No. 1","pp. 95-101",1989,
"K. Kakinuma,K. Ozawa,Y. Fujimoto,N. Akutsu,T. Oshima","Stereochemistry of the decarboxylation reaction catalyzed by 3-isopropylmalate dehydrogenase from the thermophilic bacterium Thermus thermophilus",,"J. Chem. Soc., Chem. Commun.",,,"No. 17","pp. 1190-1192",1989,
"Y. Fujimoto,Y. Ikuina,Y. Kanzawa,K. Kakinuma,N. Ikekawa","Mechanism of the boron trifluoride etherate-catalyzed rearrangement of an acyclic trisubstituted epoxide to a carbonyl compound",,"J. Chem. Soc., Chem. Commun.",,,"No. 16","pp. 1107-1109",1989,
"Y. Fujimoto,Y. Ikuina,K. Kakinuma","Mechanism of the conversion of fucosterol epoxide into desmosterol in insects. Stereochemical fate of the diastereotopic C-26 and C-27 methyl groups of the epoxide",,"J. Chem. Soc., Chem. Commun.",,,"No. 8","pp. 464-466",1989,
"Y. Fujimoto,T. Eguchi,K. Kakinuma,N. Ikekawa,M. Sahai,Y. K. Gupta","Squamocin, a new cytotoxic bis-tetrahydrofuran containing acetogenin from Annona squamosa",,"Chem. Pharm. Bull.",,"Vol. 36","No. 12","pp. 4802-4806",1988,Dec.
"K. Nakamura,T. Yamada,Y. Fujimoto,K. Kakinuma,N. Ikekawa","Synthesis of 3β,6α-dihydroxycholesta-9(11),17(20),24-trien-23-one, the aglycon of acrosome reaction-inducing steroidal saponin Co-ARIS II",,"Chem. Pharm. Bull.",,"Vol. 36","No. 8","pp. 2808-2812",1988,Aug.
"T. Eguchi,Y. Fujimoto,K. Kakinuma,N. Ikekawa,M. Sahai,M. P. Verma,Y. K. Gupta","23-Hydroxyphysalolactone, a new withanolide with a 23-hydroxyl group from Physalis peruviana (Solanaceae)",,"Chem. Pharm. Bull.",,"Vol. 36","No. 8","pp. 2897-2901",1988,Aug.
"M. Hiramoto,Y. Fujimoto,K. Kakinuma,N. Ikekawa,E. Ohnishi","Ecdysteroid conjugates in the ovaries of the silkworm, Bombyx mori: 3-Phosphates of 2,22-dideoxy-20-hydroxy-ecdysone and of bombycosterol",,"Experientia",,"Vol. 44","No. 7","pp. 623-625",1988,July
"K. Kakinuma,M. Yamaguchi,Y. Fujimoto,T. Oshima,N. Ikekawa","Stereochemistry of the biosynthesis of sn-2,3-O-diphytanyl glycerol, membrane lipid of archaebacteria Halobacterium halobium",,"J. Am. Chem. Soc.",,"Vol. 110","No. 14","pp. 4861-4863",1988,July
"Y. Fujimoto,T. Kinoshita,I. Ohya,K. Kakinuma,N. Ikekawa,M. Morisaki","Non-stereoselective conversion of the four diastereomers at the C-24 and C-25 positions of 3α,7α,12α,24-tetrahydroxy-5β-cholestan 26-oic acid into cholic acid",,"Chem. Pharm. Bull.",,"Vol. 36","No. 1","pp. 142-145",1988,Jan.
"T. Kinoshita,M. Miyata,S. M. Ismail,Y. Fujimoto,K. Kakinuma,N. Ikekawa,M. Morisaki","Synthesis and determination of stereochemistry of four diastereoisomers at the C-24 and C-25 position of 3α,7α,12α,24-tetrahydroxy-5β-cholestan-26-oic acid",,"Chem. Pharm. Bull.",,"Vol. 36","No. 1","pp. 134-141",1988,Jan.
"K. Kakinuma,N. Yamauchi,Y. Fujimoto","Electrophilic reaction on plinol C and syntheses of functionalized 2-oxabicyclo[2.2.1]heptane derivatives",,"Agricultural and Biological Chemistry",,"Vol. 52","No. 8","pp. 2049-2057",1988,
"KATSUMI KAKINUMA","Synthesis of D-(6R)-and D-(6S)-(6- ┣D12┫D1H┣D21┫D2)Glucose",,"Tetrahedron",,"Vol. 40",,"pp. 11",1984,
"KATSUMI KAKINUMA","Stereochemistry of Ribostamycin Biosynthesis, An Application of ┣D12┫D1H-NMR Spectroscopy",,"Journal of the American Chemical Society",,"Vol. 103",,"pp. 18",1981,
"KATSUMI KAKINUMA","Structure and Biosynthesis of Setomimycin, A nove 19,9'-Bianthryl Antibiotic",,"Journal of the American Chemical Society",,"Vol. 102",,"pp. 25",1980,
"柿沼勝己","選択的拮抗物質デトキシンの化学構造に関する研究",,,,,,,1972,