論文

• Satoru Watanabe, Hiroaki Ozawa, Hiroaki Kato, Kaori Nimura-Matsune, Toshifumi Hirayama, Fumitaka Kudo, Tadashi Eguchi, Katsumi Kakinuma, Hirofumi Yoshikawa. Carbon-free Production of 2-Deoxy-scyllo-inosose (DOI) in Cyanobacterium Synechococcus elongatus PCC 7942, Biosci. Biotechnol. Biochem., Vol. 82, No. 1, pp. 161-165, Jan. 2018.
• Toshifumi Hirayama, Hideyuki Tamegai, Fumitaka Kudo, Kazumasa Kojima, Katsumi Kakinuma, Tadashi Eguchi. Biosynthesis of 2-Deoxystreptamine-containing Antibiotics in Streptoalloteichus hindudtanus JCM 3268: Characterization of 2-Deoxy-scyllo-inosose Synthase, J. Antibiot., Vol. 59, No. 6, pp. 358-361, June 2006.
• Fumitaka Kudo, Takashi Kitayama, Tadashi Eguchi, Katsumi Kakinuma. Macrolactam Formation Catalyzed by the Thioesterase Domain of Vicenistatin Polyketide Synthase, Tetrahedron Lett., Vol. 47, No. 10, pp. 1529-1532, Apr. 2006.
• Fumitaka Kudo, Yasuhito Yamamoto, Kenichi Yokoyama, Tadashi Eguchi, Katsumi Kakinuma. Biosynthesis of 2-Deoxystreptamine by Three Crucial Enzymes in Streptomyces fradiae NBRC12773, J. Antibiot., Vol. 58, No. 12, pp. 766-774, Dec. 2005.
• Fumitaka Kudo, Mario Numakura, Hideyuki Tamegai, Hideki Yamamoto, Tadashi Eguchi, Katsumi Kakinuma. Extended Sequence and Functional Analysis of the Butirosin Biosynthetic Gene Cluster in Bacillus circulans SANK 72073, J. Antibitot., Vol. 58, No. 6, pp. 373-379, June 2005.
• Kenichi Yokoyama, Fumitaka Kudo, Mieko Kuwahara, Kousuke Inomata, Hideyuki Tamegai, Tadashi Eguchi, Katsumi Kakinuma. Stereochemical Recognition of Doubly Functional Aminotransferase in 2-Deoxystreptamine Biosynthesis, J. Am. Chem. Soc., Vol. 127, No. 16, pp. 5869-5874, May 2005.
• Fumitaka Kudo, Kenichi Kawabe, Hisako Kuriki, Tadashi Eguchi, Katsumi Kakinuma. A New family of Pathways for Glucose-1-phosphate/Glucosamine-1-phosphate Nucleotidylyltransferase in the Biosynthetic Antibiotics, J. Am. Chem. Soc., Vol. 127, No. 6, pp. 1711-1718, Mar. 2005.
• E. Nango, T. Eguchi, K. Kakinuma. Active Site Mapping of 2-Deoxy-scyllo-inosose Synthase, the Key Starter Enzyme in the Biosynthesis of 2-Deoxystreptamine. Mechanism-based Inhibition and Identification of Lys-141 as an Entrapped Nucleophile, J. Org. Chem., Vol. 69, No. 3, pp. 593-600, 2004.
• S. Tohyama, T. Eguchi, R. P. Dhakal, T. Akashi, M. Otsuka, K. Kakinuma. Genome-Inspired Search for New Antibiotics. Isolation and Structure Determination of New 28-Membered Polyketide Macrolactones, Halstoctacosanolide A and B, from Streptomyces halstedii HC34, Tetrahedron, Vol. 60, No. 18, pp. 3999-4005, 2004.
• Y. Ogasawara, K. Katayama, A. Minami, M. Otsuka, T. Eguchi, K. Kakinuma. Cloning, Sequencing, and Functional Analysis of the Biosynthetic Gene Cluster of Macrolactam Antibiotic Vicenistatin in Streptomyces halstedii, Chem. Biol., Vol. 11, No. 1, pp. 79-86, 2004.
• T. Eguchi, K. Yamamoto, K. Mizoue, K. Kakinuma. Structure Revision of FD-891, a 16-Membered Macrolide Antibiotic, J. Antibiot., Vol. 57, No. 2, pp. 156-157, 2004.
• Eriko Nango, Fumitaka Kudo, Tadashi Eguchi, Katsumi Kakinuma. Reaction Stereochemistry of 2-Deoxy-scyllo-inosose Synthase. The Key Enzyme in the Biosynthesis of 2-Deoxystreptamine-containing Aminoglycoside Antibiotics, Chem. Lett., Vol. 32, No. 5, pp. 438-439, May 2003.
• E. Nango, F. Kudo, T. Eguchi, K. Kakinuma. Reaction Stereochemistry of 2-Deoxy-scyllo-inosose Synthase. The Key Enzyme in the Biosynthesis of 2-Deoxystreptamine-containing Aminoglycoside Antibiotics, Chem. Lett., Vol. 32, No. 5, pp. 438-439, 2003.
• T. Yukita, H. Nishida, T. Eguchi. K. Kakinuma. Biosynthesis of (2R)-4-Amino-2-hydroxybutyric Acid, Unique and Biologically Significant Substituent in Butirosin, J. Antibiotics, Vol. 56, No. 5, pp. 497-500, 2003.
• T. Eguchi, Y. Nishimura, K. Kakinuma. Importance of Isopropylidene Functionality of Di-O-Geranylgeranyl Glyserol for the Biosynthesis of Archaeal Macrocyclic Membrane Lipids, Tetrahedron Lett., Vol. 44, No. 16, pp. 3275-3279, 2003.
• T. Eguchi, Y. Dekishima, Y. Hamano, T. Dairi, H. Seto, K. Kakinuma. A New Approach for the Investigation of Isoprenoid Biosynthesis Featuring Pathway Switching, Deuterium Hyperlabeling and 1H NMR Spectroscopy. The Reaction Mechanism of a Novel Streptomyces Diterpene Cyclase, J. Org. Chem., Vol. 68, No. 14, pp. 5433-5438, 2003.
• T. Eguchi, E. Watanabe, K. Kakinuma. Practical Enantioselective Synthesis of Fully Deuterated (R)-Mevalonolactone, Tetrahedron, Vol. 59, pp. 6035-6038, 2003.
• 為我井秀行, 柿沼勝己. 「もの」が秘める可能性　－　アミノグリコシド抗生物質の生合成に学ぶ, 化学と生物, Vol. 41, No. 11, pp. 763-771, 2003.
• Hideyuki Tamegai, Eriko Nango, Ayumi Koike-Takeshita, Fumitaka Kudo, Katsumi Kakinuma. Significance of the 20 kDa Subunit of Heterodimeric 2-Deoxy-scyllo-inosose Synthase for the Biosynthesis of Butirosin Antibiotics in Bacillus circulans, Bioscience, Biotechnololgy, and Biochemistry, Vol. 66, No. 7, pp. 1538-1545, July 2002.
• Y. Matsushima, H. Itoh, T. Nakayama, S. Horiuchi, T. Eguchi, K. Kakinuma. Enantioselective Total Synthesis of Vicenistatin, A Novel 20-Membered Macrocyclic Lactam Antitumor Antibiotic, Perkin 1, Vol. 2002, No. 7, pp. 949-958, 2002.
• H. Tamegai, E. Nango, M. Kuwahara, H. Yamamoto, Y. Ota, H. Kuriki, T. Eguchi, K. Kakinuma. Identification of L-Glutamine:2-Deoxy-scyllo-inosose Aminotransferase Required for the Biosynthesis of Butirosin in Bacillus circulans, J. Antibiot., Vol. 55, No. 8, pp. 707-714, 2002.
• H. Tamegai, T. Eguchi, K. Kakinuma. First Identification of Streptomyces genes involved in the Biosynthesis of 2-Deoxy-streptamine-containing Aminoglycoside Antibiotics. Genetic and Evolutionary Analysis of L-Glutamine:2-Deoxy-scyllo-inosose Aminotransferase genes, J. Antibiot., Vol. 55, No. 11, pp. 1016-1018, 2002.
• T. Eguchi, K. Kobayashi, H. Uekusa, Y. Ohashi, K. Mizoue, Y. Matsushima, K. Kakinuma. Stereostructure of a Novel Cytotoxic 18-Membered Macrolactone Antibiotic FD-891, Org. Lett., Vol. 4, No. 20, pp. 3383-3386, 2002.
• T. Eguchi, S. Sasaki, Zhen Huang, K. Kakinuma. Importance of Specific Hydrogen-Bonding Donor-Acceptor Interactions for the Key Carbocycle-forming Reaction Catalyzed by 2-Deoxy-scyllo-inosose Synthase in the Biosynthesis of 2-Deoxystreptamine-containing Aminocyclitol Antibiotics, J. Org. Chem., Vol. 67, No. 12, pp. 3979-3984, 2002.
• H. Tamegai, E. Nango, A. Koike-Takeshita, F. Kudo, K. Kakinuma. Significance of the 20k-Da Subunit of Heterodimeric 2-Deoxy-scyllo-inosose Synthase for the Biosynthesis of Butirosin Antibiotics in Bacillus circulans, Biosci. Biotechnol. Biochem., Vol. 66, No. 7, pp. 1538-1545, 2002.
• K. Arakawa, T. Eguchi, K. Kakinuma. 36-Membered Macrocyclic Diether Lipid is Advantageous for Archaea to Thrive under the Extreme Thermal Environments, Bull. Chem. Soc. Jpn, Vol. 74, No. 2, pp. 347-356, 2001.
• M. Fujita, H. Tamegai, T. Eguchi, K. Kakinuma. Novel Substrate-Specificity of Designer 3-Isopropylmalate Dehydrogenase from Thermus thermophilus HB8, Biosci. Biotechnol. Biochem., Vol. 65, No. 12, pp. 2695-2700, 2001.
• K. Kakinuma, Y. Dekishima, Y. Matsushima, T. Eguchi, N. Misawa, M. Takagi, T. Kuzuyama, H. Seto. New Approach to Multiply Deuterated Isoprenoids Using Triply Engineered Escherichia coli and Its Potential for Mechanistic Enzymology, J. Am. Chem. Soc., Vol. 123, No. 6, pp. 1238-1239, 2001.
• Y. Matsushima, T. Nakayama, M. Fujita, R. Bhandari, T. Eguchi, K. Shindo, K. Kakinuma. Isolation and Structure Elucidation of Vicenistatin M, and Importance of the Vicenisamine Aminosugar for Exerting Cytotoxicity of Vicenistatin, J. Antibiot., Vol. 54, No. 3, pp. 211-219, 2001.
• Y. Matsushima, T. Nakayama, S. Toyama, T. Eguchi, K. Kakinuma. Versatile Route to 2,6-Dideoxyamino Sugars from Non-sugar Materials: Syntheses of Vicenisamine and Kedarosamine, J. Chem. Soc. Perkin Trans. I, No. 6, pp. 569-577, 2001.
• Y. Dekishima, T. Eguchi, K. Kakinuma, Y. Matsushima, N. Misawa, T. Kuzuyama, H. Seto. Preparation of Multiply Deuterated Carotenoids by Triply Engineered Escherichia coli with Perdeuterated Mevalonate, Carotenoid Science, Vol. 4, No. 1, pp. 64-65, 2001.
• K. Arakawa, T. Eguchi, K. Kakinuma. Highly Thermostable Liposome from 72-Membered Macrocyclic Tetraether Lipid: Importance of 72-Membered Lipid for Archaea to Thrinve under Hyperthermal Environments, Chem. Lett., No. 5, pp. 440-441, 2001.
• S. Sakuda, Y. Sugiyama, Z.-Y. Zhou, H. Takao, H. Ikeda, K. Kakinuma, Y. Yamada, H. Nagasawa. Biosynthetic Studies on the Cyclopentane Ring Formation of Allosamizoline, an Aminocyclitol Component of the Chitinase Inhibitor Allosamidin, J. Org. Chem., Vol. 66, No. 10, pp. 3356-3361, 2001.
• H. Nishida, T. Eguchi, K. Kakinuma. Amino Acid Starter Unit in the Biosynthesis of Macrolactam Polyketide Antiumor Antibiotic Vicenistatin, Tetrahedron, Vol. 57, pp. 8237-8242, 2001.
• Yasumasa Ota, Hideyuki Tamegai, Fumitaka Kudo, Hisako Kuriki, Aumi Koike-Takeshita, Tadashi Eguchi, Katsumi Kakinuma. Butirosin-biosynthetic Gene Cluster from Bacillus circulans, J. Antibiot., Vol. 53, No. 10, pp. 1158-1167, Oct. 2000.
• Katsumi Kakinuma, Eriko Nango, Fumitaka Kudo, Yoshitaka Matsushima, Tadashi Eguchi. An Expeditious Chemo-enzymatic Route from Glucose to Catechol by the Use of 2-Deoxy-scyllo-inosose Synthase, Tetrahedron Letters, Vol. 41, No. 12, pp. 1935-1938, Apr. 2000.
• 柿沼勝己. バイオマスを化学資源に　－二次代謝酵素の可能性－, バイオサイエンスとインダストリー, Vol. 58, No. 12, pp. 39-40, 2000.
• M. Otsuka, M. Fujita, Y. Matsushima, T. Eguchi, K. Shindo, K. Kakinuma. Biosynthetic Pathway of Macrolactam Polyketide Glycoside Antitumor Antibiotic Vicenistatins., Tetrahedron, Vol. 56, No. 42, pp. 8281-8286, 2000.
• Y. Ota, H. Tamegai, F. Kudo, H. Kuriki, A. Koike-Takeshita, T. Eguchi, K. Kakinuma. Butirosin Biosynthetic Gene Cluster from Bacillus circulans, J. Antibiot., Vol. 53, No. 10, pp. 1158-1167, 2000.
• T. Eguchi, K. Arakawa, K. Kakinuma, G. Rapp, S. Ghosh, Y. Nakatani, G. Ourisson. Giant Vesicles from 72-Membered Macrocyclic Archaeal Phospholipid Analogues. Initiation of Vesicle Formation by Molecular Recognition between Membrane Components, Chem. Eur. J. , Vol. 6, No. 18, pp. 3351-3358, 2000.
• O. Dannenmuller, K. Arakawa, T. Eguchi, K. Kakinuma, S. Blanc, A.-M. Albrecht, M. Schmutz, Y. Nakatani, G. Ourisson. Membrane Properties of Archaeal Macrocyclic Diether Phospholipids, Chem., Eur. J., Vol. 6, No. 4, pp. 645-654, 2000.
• M. Fujita, Y. Toyooka, H. Tamegai, T. Eguchi, K. Kakinuma. Arg-94 is crucial to the catalysis of 3-isopropylmalate dehydrogenase from Thermus thermophilus HB8, J. Mol. Cat. B: Enzymatic., Vol. 9, pp. 149-155, 2000.
• T. Eguchi, H. Takyo, M. Morita, K. Kakinuma, Y. Koga;. Unusual Double-Bond Migration as Plausible Key Reaction in the Biosynthesis of the Isoprenoidal Membrane Lipids of Methanogenic Archae, Chem. Commun., No. 16, pp. 1545-1546, 2000.
• K. Kakinuma, E. Nango, F. Kudo, Y. Matsushima, T. Eguchi. An Expeditious Chemo-Enzymatic Route from Glucose to Catechol by the Use of 2-Deoxy-scyllo-inosose Synthase, Tetrahedron Lett., Vol. 41, No. 12, pp. 1935-1938, 2000.
• T. Eguchi, S. Kanai, K. Kakinuma, T. Okazaki, K. Mizoue. Synthesis of NG-061 and Its Analogs, and Their Biological Evaluation as an Enhancer of Nerve Growth Factor, Chem. Pharm. Bull., Vol. 48, No. 10, pp. 1470-1473, 2000.
• Fumitaka Kudo, Yoshihiro Hosomi, Hideyuki Tamegai, Katsumi Kakinuma. Purification and Characterization of 2-Deoxy-scyllo-inosose Synthase Derived from Bacillus circulans. A Crucial Carbocyclization Enzyme in the Biosynthesis of 2-Deoxystreptamine-containing Aminoglycoside Antibiotics, Journal of Antibiotics, Vol. 52, No. 2, pp. 81, Feb. 1999.
• 127) A. Chiba, T. Aoyama, R. Suzuki, T. Eguchi, T. Oshima, K. Kakinuma. Synthetic and Mechanistic Studies of (2R,3S)-3-Vinylmalic Acid as A Mechanism-based Inhibitor of 3-Isopropylmalate Dehydrogenase, J. Org. Chem., Vol. 64, No. 17, pp. 6159-6165, 1999.
• F. Kudo, Y. Hosomi, H. Tamegai, K. Kakinuma. Purification and Characterization of 2-Deoxy-scyllo-inosose Synthase Derived from Bacillus circulans. A Crucial Carbocyclization Enzyme in the Biosynthesis of 2-Deoxystreptamine-containing Aminoglycoside Antibiotics, J. Antibiot., Vol. 52, No. 2, pp. 81-88, 1999.
• 129) M. Ito, N. Sakai, K. Ito, F. Mizobe, K. Hanada, K. Mizoue, R. Bhandari, T. Eguchi, K. Kakinuma. A Novel Fungal Metabolite NG-061 Enhances and Mimics Neurotrophic Effect of Nerve Growth Factor (NGF) on Neurite Outgrowth in PC12 Cells, J. Antibiot., Vol. 52, No. 3, pp. 224-230, 1999.
• R. Bhandari, T. Eguchi, A. Sekine, Y. Ohashi, K, Kakinuma. Structure, of NG-061, A Novel Potentiator of Nerve Growth Factor (NGF) Isolated from Penicillium miniolutem F-4647, J. Antibiot., 52 [3], 231-234 (1999), Vol. 52, No. 3, pp. 231-234, 1999.
• F. Kudo, H. Tamegai, T. Fujiwara, U. Tagami, K. Hirayama, K. Kakinuma. Molecular Cloning of the Gene for the Key Carbocycle-forming Enzyme in the Biosynthesis of 2-Deoxystreptamine-containing Aminocyclitol Antibiotics and Its Comparison with Dehydroquinate Synthase, J. Antibiot., Vol. 52, No. 6, pp. 559-571, 1999.
• A. Chiba, T. Eguchi, T. Oshima, K. Kakinuma. Synthesis of Cyclopropane Substrate Analog for 3-Isopropylmalate Dehydrogenase and Its Mechanism-Based Inhibition, Tetrahedron, Vol. 55, pp. 2927-2936, 1999.
• K. Arakawa, H. Kano, T. Eguchi, Y. Nishiyama, K. Kakinuma. Significance of the 72-Membered Macrocyclic Structure Found in Archaeal Membrane Lipids: Model Studies the Macrocyclic Tetraether Diphospholipids by Calorimetric, 31P-NMR, and Electron Microscopic Analyses, Bull. Chem. Soc. Jpn., Vol. 72, No. 7, pp. 1575-1581, 1999.
• A. Chiba, T. Eguchi, T. Oshima, K. Kakinuma. Coenzyme Activity of NAD Analogs for 3-Isopropylmalate Dehydrogenase from Thermus thermophilus HB8, Biosci. Biotechnol. Biochem., Vol. 63, No. 9, pp. 1647-1649, 1999.
• A. Chiba, N. Arai, T. Eguchi, K. Kakinuma. 3-Isopropylidenemalic Acid : A Mechanism-based Inhibitor of 3-Isopropylmalate Dehydrogenase, Chem. Lett., No. 12, pp. 1313-1314, 1999.
• 柿沼勝己. 生合成研究における有機合成の重要性, ファルマシア, Vol. 35, No. 7, pp. 700-705, 1999.
• 江口正, 荒川賢治, 柿沼勝己. ３０員環を越す巨大な環状化合物の合成：古細菌細胞膜の脂質分子を中心として, 有機合成化学協会誌, Vol. 57, No. 9, pp. 784-797, 1999.
• T. Eguchi, K. Kondo, K. Kakinuma, H. Uekusa, Y. Ohashi, K. Mizoue, Y.-F. Qiao. Unique Solvent-dependent Atropisomerism of A Novel Cytotoxic Naphthoxanthene Antibiotic FD-594, J. Org. Chem., Vol. 64, No. 15, pp. 5371-5376, 1999.
• Noriaki Iwase, Fumitaka Kudo, Noriaki Yamauchi, Katsumi Kakinuma. Biochemical Studies on 2-Deoxy-scyllo-inosose, an Early Intermediate in the Biosynthesis of 2-Deoxystreptamine. VII. Substrate Specificity of 2-Deoxy-scyllo-inosose Synthase, the Starter Enzyme for 2-Deoxystreptamine Biosynthesis, toward Deoxyglucose-6-phosphates and Proposed Mechanism, Bioscience, Biotechnology, and Biochemistry, Vol. 62, No. 12, pp. 2396-2407, Dec. 1998.
• T. Eguchi, M. Fukuda, Y. Toyooka, K. Kakinuma. Rational De Novo Design of NADH Mimic for Stereoselective Reduction Based on Molecular Orbital Calculation, Tetrahedron, Vol. 54, pp. 705-714, 1998.
• H. Morii, T. Eguchi, M. Nishihara, K Kakinuma, H. Konig, Y. Koga. A Novel Ether Core Lipid with an H-Shaped C┣D280┫D2-Isoprenoid Hydrocarbon Chain from the Hyperthermophilic Methanogen Methanothermus fervidus, Biochim. Biophys. Acta, Vol. 1390, No. 3, pp. 339-345, 1998.
• KATSUMI KAKINUMA. Overproduction and Substrate Specificity of 3-Isopropylmalate Dehydrogenase from Thiobacillus ferrooxidans, Biosci. Biotechnol. Biochem., Vol. 62, No. 2, pp. 372-373, 1998.
• KATSUMI KAKINUMA. Structural Diversity of Membrane Core Lipid of Extreme Halophile, Biosci. Biotechnol. Biochem., Vol. 62, No. 3, pp. 596-598, 1998.
• T. Eguchi, M. Morita, K. Kakinuma. Multi-gram Synthesis of Mevalonolactone-d┣D29┫D2 and Its Application to the Stereo-chemical Analysis of Saturation Reaction in the Biosynthesis of 2,3-Di-O-phytanyl-sn-glycerol Core of Archaeal Membrane Lipid as Studied by ┣D11┫D1H-NMR, J. Am. Chem. Soc., Vol. 120, No. 22, pp. 5427-5433, 1998.
• T. Eguchi, K. Ibaragi, K. Kakinuma. Total Synthesis of Archaeal 72-Membered Macrocyclic Tetraether Lipids, J. Org. Chem., Vol. 63, No. 8, pp. 2689-2698, 1998.
• KATSUMI KAKINUMA. Isolation and Characterization of A New Pyrano[4', 3' : 6,7]naphtho[1,2-b]xanthene Antibiotic FD-594, J. Antibiot., Vol. 51, No. 3, pp. 282-287, 1998.
• K. Kondo, T. Eguchi, K. Kakinuma, K. Mizoue, Y.-F. Qiao. Structure and Biosynthesis of FD-594 ; A New Antitumor Antibiotic, J. Antibiot., Vol. 51, No. 3, pp. 288-295, 1998.
• KATSUMI KAKINUMA. Absolute Stereochemistry of Vicenistatin, A Novel 20-Membered Macrocyclic Lactam Antitumor Antibiotic, Tetrahedron Lett., Vol. 39, No. 20, pp. 3181-3184, 1998.
• M. Otsuka, T. Eguchi, K. Shindo, K. Kakinuma. Non-Fatty Acyl Polyketide Starter in the Biosynthesis of Vicenistatin, an Antitumor Macrolactam Antibiotic, Tetrahedron Lett., Vol. 39, No. 20, pp. 3185-3188, 1998.
• KATSUMI KAKINUMA. Enantioselective and Convergent Synthesis of the 20-Membered Lactam Aglycon of Vicenistatin Antitumor Antibiotic, J. Antibiot., Vol. 51, No. 7, pp. 688-691, 1998.
• KATSUMI KAKINUMA. Solvent-dependent Stereochemical Anomaly in the Nucleophilic Addition of Ester-derived Enolate to Bicyclo[3,3,0]octan-2-one System of Diacetone glucos-3-ulose, Chem. Lett., Vol. 1998, No. 6, pp. 475-476, 1998.
• KATSUMI KAKINUMA. An Olefin Metathesis Approach to 36-and 72-Membered Archaeal Macrocyclic Membrane Lipids, J. Org. Chem., Vol. 63, No. 14, pp. 4741-4745, 1998.
• KATSUMI KAKINUMA. Tightly Packed Membranes Composed of 36-Membered Macrocyclic Diether Phospholipids Found in Archae Growing under Deep-Sea Hydrothermal Vents, Chem. Lett., Vol. 1998, No. 9, pp. 901-902, 1998.
• KATSUMI KAKINUMA. Substrate Specificity of 2-Deoxy-scyllo-inosose Synthase, the Starter Enzyme in 2-Deoxystreptamine Biosynthesis, toward Deoxyglucose-6-phosphates and Proposed Mechanism, Biosci. Biotechnol. Biochem., pp. 62, 1998.
• KATSUMI KAKINUMA. Specific Deuterium Labeling of Archaeal 36-Membered Macrocyclic Diether Lipid, Bull. Chem. Soc. Jpn, pp. 71, 1998.
• KATSUMI KAKINUMA. Biosynthesis of Riboflavin. Stereochemistry of the 3,4-Dihydroxy-2-butanone 4-phosphate Synthase Reaction, J. Org. Chem., pp. 63, 1998.
• F. Kudo, N. Yamauchi, R. Suzuki, K. Kakinuma. Kinetic Isotope Effect and Reaction Mechanism of 2-Deoxy-scyllo-inosose Synthase Derived from Butirosin-producing Bacillus circulans, J. Antibiot., Vol. 50, No. 5, pp. 424-429, 1997.
• KATSUMI KAKINUMA. Diacetone-glucose Architechture as a Chirality Template. Part9. Enantioselective Synthesis of (R)-Mevalolactone and (R)-[┣D12┫D1H┣D29┫D2]Mevalolactone on Carbohydrate Template., J. Chem. Soc. Perkin I, pp. 891-895, 1997.
• KATSUMI KAKINUMA. Total Synthesis of Archaeal 36-Membered Macrocyclic Diether Lipid, J. Org. Chem. ,, Vol. 36, No. 7, pp. 1924-1933, 1997.
• KATSUMI KAKINUMA. Synthesis of Conformationally Restricted Substrate Analogs and Their Interaction with 3-Isopropylmalate Dehydrogenase Derived from Thermophile Thermus thermophilus, Tetrahedron, Vol. 53, No. 10, pp. 3537-3544, 1997.
• KATSUMI KAKINUMA. Synthetic Studies of Archaeal Macrocyclic Tetraether Lipids : Practical Synthesis of 72-Membered Tetraether Model Compounds, Bull. Chem. Soc. Jpn, Vol. 70, No. 10, pp. 2545-2554, 1997.
• KATSUMI KAKINUMA. Remote Asymmetric Induction Observed in the Alkylation of Propionate Attached to Carbohydrate Template, Terahedron Lett.,, Vol. 37, No. 12, pp. 2061-2062, 1996.
• KATSUMI KAKINUMA. The First Synthesis of 72-Membered Macrocyclic Model Lipids Desmethylated Analogues to Membrane Lipids of Archaefacteria Growing in Etreme Environments, J.Chem.Soc.Chem.Commun, pp. 365-366, 1996.
• KATSUMI KAKINUMA. A Versatile Synthon for Chirelly β-Deuterated L-Amino Acids and Synthesis of (3R)-and(3S)-[3-┣D12┫D1H┣D21┫D2]-L-Serine, Biosci.Biotech.Biochem.,, Vol. 60, No. 7, 1996.
• KATSUMI KAKINUMA. Synthesis of DL-threo-3-(1-Fluoro-1-methylethyl)-and DL-threo-3-(1,1-Difluoroethyl)malic Acids. Mechanistic Studies of 3-Isopropylmalate Dehydrogenase, J. Chem. Soc. Perkin I, No. 17, pp. 1905-1912, 1995.
• KATSUMI KAKINUMA. Enzymatic Carbocycle Formation in Microbial Secondary Metabolism. The Mechanism of 2-Deoxy-scyllo-inosose Synthase Reaction As a Crucial Step of the 2-Deoxystreptamine Biosynthesis in Streptomyces fradiae, J. Org. Chem., Vol. 60, No. 37, pp. 5614-5619, 1995.
• KATSUMI KAKINUMA. NADH Mimics on Diacetone-D-Glucose : Stereoselective Biomimetic Reduction of Benzoylformate and Interpretation of Chirality Transfer Deduced by Molecular Orbital Approach, Tetrahedron, Vol. 51, No. 23, pp. 6459-6474, 1995.
• R. K. Mukherjee, Y. Fujimoto, K. Kakinuma. (1-ω-Hydroxyfattyacyl)glycerols and two flavanols from Cinnamomum camphora, Phytochemistry, Vol. 37, No. 6, pp. 1641-1643, Dec. 1994.
• M. Nagakari, T. Kushiro, T. Matsumoto, N. Tanaka, K. Kakinuma, Y. Fujimoto. Incorporation of acetate and cholesterol into 20-hydroxyecdysone by hairy root clone of Ajuga reptans var. atropurpurea, Phytochemistry, Vol. 36, No. 4, pp. 907-910, July 1994.
• Y. Fujimoto, C. Murasaki, T. Eguchi, K. Kakinuma, C. P. Dutta. Formation of 9,25-cyclofernane by reductive homoallylic cyclization of fern-9(11)-en-25-ol mesylate, Chem. Pharm. Bull., Vol. 42, No. 6, pp. 1334-1335, June 1994.
• M. Sahai, M. Singh, Y. K. Gupta, S. Akashi, R. Yuji, K. Hirayama, H. Asaki, H. Araya, N. Hara, T. Eguchi, K. Kakinuma, Y. Fujimoto. Annonaceous acetogenins from the seeds of Annona squamosa. Adjacent bis-tetrahydrofuranic acetogenins, Chem. Pharm. Bull., Vol. 42, No. 6, pp. 1163-1174, June 1994.
• Y. Fujimoto, C. Murasaki, H. Shimada, S. Nishioka, K. Kakinuma, S. Singh, M., Singh, Y. K. Gupta, M. Sahai. Annonaceous acetogenins from the seeds of Annona squamosa. Non-adjacent bis-tetrahydrofuranic acetogenins, Chem. Pharm. Bull., Vol. 42, No. 6, pp. 1175-1184, June 1994.
• KATSUMI KAKINUMA. 3β-Hydroxy-5β-cholest-7-en-6-one as an Intermediate of 20-Hydroxyecdysone Biosynthesis in Hairy Root Culture of Ajuga reptans var. atropurpurea, J. Chem. Soc. Chem. Commun., Vol. 15, pp. 1761-1762, 1994.
• KATSUMI KAKINUMA. Crystal Structure of Ethyl(2S┣D1*┫D1, 3R┣D1*┫D1)-2-Benzoyloxy-4,4-difluoro-3-(4-methoxyphenyl)-pentanoate, Analytical Sci.,, Vol. 10, pp. 519-520, 1994.
• KATSUMI KAKINUMA. Mechanistic and Stereochemical Studies on Ferrier Reaction by Means of Chirally Deuterated Glucose, Tetrahedron, Vol. 50, No. 14, pp. 4125-4136, 1994.
• KATSUMI KAKINUMA. Synthesis of 2-O-Methyl Ether and 1-Carboxamide Derivatives of (2R, 3S)-3-Isopropylmalic Acid and Their Interaction with Thermophilic 3-Isopropylmalate Dehydrogenase, Biosci. Biotech. Biochem., Vol. 58, No. 8, pp. 870-873, 1994.
• KATSUMI KAKINUMA. Annonaceous Acetogenins from the Seeds of Annona squamosa. Non-adjacent Bistetrahedrofuranic Acetogenins, Chem. Pharm. Bull., Vol. 42, No. 6, pp. 1175-1184, 1994.
• KATSUMI KAKINUMA. Incorporation of Acetate and Chlosterol into 20-Hydroxyecdysone with Hairy Root Clone of Ajuga reptans var. atropurpurea, Phytochemistry, Vol. 36, No. 4, pp. 907-910, 1994.
• KATSUMI KAKINUMA. Annonaceous Acetogenins from the Seeds of Annona squamosa. Adjacent Bis-tetrahedro-furanic Acetogenins, Chem. Pharm. Bull., Vol. 42, No. 6, pp. 1163-1174, 1994.
• KATSUMI KAKINUMA. Annonaceous Acetogenins from the Seeds of Annona squamosa. Nonadjacent Bis-tetrahedrofuranic Acetogenins, Chem. Pharm. Bull., Vol. 42, No. 6, pp. 1157-1184, 1994.
• KATSUMI KAKINUMA. Synthesis of 2-O-Methyl Ether and 1-Corboxamide Derivatives of (2R,3R)-3-Isopropylmalic Acid and Their Interaction with Thermoplilic 3-Isopropylmalate Dehydrogenase, Biosci.Biotech.Biochem.,, Vol. 58, No. 8, pp. 870-873, 1994.
• KATSUMI KAKINUMA. Mechamistic and Stereochmical Studies on Ferrier Reaction by Meano of Chirally Deuterated Glucose, Tetrahedron, Vol. 50, No. 14, pp. 4125-4136, 1994.
• KATSUMI KAKINUMA. Formation of 9,25-Cyclofernane by Reductive Homoallylic Cyclization of Fern-9(11)-en-25-ol Mesylate, Chem. Pharm. Bull., Vol. 42, No. 6, pp. 1334-1335, 1994.
• KATSUMI KAKINUMA. (1-ω-Hydroxyfattyacyl)glycerols and Two Flavanols from Cinnamomum camphora, Phytochemistry, Vol. 37, No. 6, pp. 1641-1643, 1994.
• M. Nagakari, T. Kushiro, T. Yagi, T. Matsumoto, N. Tanaka, K. Kakinuma, Y. Fujimoto. 3β-Hydroxy-5β-cholest-7-en-6-one as an intermediate of 20-hydroxyecdysone biosynthesis in a hairy root culture of Ajuga reptans var. atropurpurea, J. Chem. Soc., Chem. Commun., No. 15, pp. 1761-1762, 1994.
• C. P. Dutta, J. Banerjee, G. Datta, U. K. Som, T. Eguchi, C. Murasaki, K. Kakinuma, Y. Fujimoto. Tuberosic acid, a pentacyclic triterpene from Nephrolepsis tuberosa, Phytochemistry, Vol. 33, No. 1, pp. 240-242, Apr. 1993.
• J. Mungarulire, R. M. Munabu, C. Murasaki, T. Eguchi, Y. Fujimoto, K. Kakinuma, K. Kobayashi, M. Uramoto, N. Ikekawa. A novel steroidal saponin, pogosterol from Vernonia pogosperma, Chem. Pharm. Bull., Vol. 41, No. 2, pp. 411-413, Feb. 1993.
• KATSUMI KAKINUMA. An Alkalophilic Bacillus Produces 2-Phenylethylamine, Appl. Environ. Microbiol., Vol. 59, No. 8, pp. 2720-2722, 1993.
• KATSUMI KAKINUMA. A Novel Steroidal Sapogenin, Pogosterol from Vernonia pogosperma, Chem. Pharm. Bull., Vol. 41, No. 2, pp. 411-413, 1993.
• KATSUMI KAKINUMA. The Overman Rearrangement on a Diacetone-D-Glucose Template : Kinetic and Theoretical Studies on the Chirality Transcription, Tetrahedron, Vol. 49, No. 21, pp. 4527-4540, 1993.
• KATSUMI KAKINUMA. Direct Closure of a 36-Membered Ring Using the McMurry Couplin : Synthetic Studies on the Macrocyclic Archaebacterial Membrane Lipids, Tetrahedron Lett., Vol. 34, No. 13, pp. 2175-2178, 1993.
• KATSUMI KAKINUMA. Chemical Transformation of Gilvocarcin V. Modification of the Side-chain, J. Antibiot., Vol. 46, No. 6, pp. 985-991, 1993.
• KATSUMI KAKINUMA. Tuberosic Acid, A Pentacyclic Triterpene from Nephrolepsis tuberosa, Phytochemistry, Vol. 33, No. 1, pp. 240-242, 1993.
• KATSUMI KAKINUMA. Enantioselective Synthesis of (2R, 3S)-3-Alkylmalic Acids, Competent Substrates of 3-Isopropylmalate Dehydrogenase, Biosci. Biotech. Biochem., Vol. 57, No. 11, pp. 1916-1923, 1993.
• KATSUMI KAKINUMA. Kinetic Analysis on the Substrate Specificity of 3-Isopropylmalate Dehydrogenase, FEBS Lett., Vol. 332, No. 1-2, pp. 35-36, 1993.
• KATSUMI KAKINUMA. Biochemical Studies on 2-Deoxy-scyllo-inosose, An Early Intermediate in the Biosynthesis of 2-Deoxystreptamine. IV. A Clue to the Mechanistic Similarity of 2-deoxy-scyllo-inosose Synthase in the 2-Deoxystreptamine Biosynthesis to Dehydroquinate Synthase, J. Antibiot., Vol. 46, No. 12, pp. 1916-1918, 1993.
• KATSUMI KAKINUMA. Remarkable Reversal of Stereoselectivity in Wittig-Type Olefinations of a-Fluorinated Alkyl Aryl Ketones, Tetrahedron Lett., Vol. 33, No. 38, pp. 5545-5546, 1992.
• KATSUMI KAKINUMA. Confirmation of ┣DBIn Vitro(/)-┫DB Synthesis of 2-Deoxy-┣DBScyllo(/)-┫DB-inosose, the Earliest Intermediate in the Biosynthesis of 2-Deoxystreptamine Using Cell-Free Preparation of ┣DBStreptomycesfradiae(/)-┫DB, Journal of Antibiotics, Vol. 45, pp. 5, 1992.
• KATSUMI KAKINUMA. The Fate of the Hydrogens of D-Glucose during the Lipid Biosynthesis and Stereochemistry of the Triose-phosphate Isomerase Reaction in Archaebacteria Halobacterium halobium, Tetrahedron Lett., Vol. 33, No. 43, pp. 6479-6482, 1992.
• KATSUMI KAKINUMA. Confirmation of In Vitro Synthesis of 2-Deoxy-scyllo-inosose, the Earliest Intermediate in the Biosynthesis of 2-Deoxystreptamine, Using Cell-Free Preparation of Streptomyces fradiae, J. Antibiot., Vol. 45, No. 5, pp. 774-780, 1992.
• KATSUMI KAKINUMA. Biochemical Studies on 2-Deoxy-scyllo-inosose, An Early Intermediate in the Biosynthesis of 2-Deoxystreptamine. II. Quantitative Analysis of 2-Deoxy-scyllo-inosose, J. Antibiot., Vol. 45, No. 5, pp. 767-773, 1992.
• KATSUMI KAKINUMA. Biochemical Studies on 2-Deoxy-scyllo-inosose, An Early Intermediate in the Biosynthesis of 2-Deoxystreptamine. I. Chemical Synthesis of 2-Deoxy-scyllo-inosose and [2,2-┣D12┫D1H┣D22┫D2]-2-Deoxy-scyllo-inosose, J. Antibiot., Vol. 45, No. 5, pp. 756-766, 1992.
• KATSUMI KAKINUMA. Diacetone Glucose Architecture as a Chirality Template. II. Versatile Synthon for the Chiral Deuterium Labeling and Synthesis of All Diastereoisomers of Chirally Monodeuterated Glycerol, Tetrahedron, Vol. 48, No. 18, pp. 3763-3774, 1992.
• KATSUMI KAKINUMA. Enantiocontrol by Intrinsic Antiparallel Double Repulsion on Diacetone-D-Glucose Template. Enantioselective Synthesis of Alanine and Chirally Deuterated Glycine, Tetrahedron Letters, Vol. 32, pp. 41, 1991.
• KATSUMI KAKINUMA. Synthesis of [19-┣D113┫D1C]-1α-Hydroxyvitamin D┣D23┫D2 and ┣D113┫D1C-NMR Analysis of the Conformational Equilibrium of the A-ring, Bioorganic. Chem., Vol. 19, pp. 327-332, 1991.
• KATSUMI KAKINUMA. Fern-9(11)-en-25-oic Acid, A Triterpene from Adiantum venustum, Phytochemistry, Vol. 30, No. 10, pp. 3478-3480, 1991.
• KATSUMI KAKINUMA. Diacetone Glucose Architecture as a Chirality Template I. Crucial Effects of the Intramolecular Oxygens upon the LiAlH┣D24┫D2 Reduction on the Propargyl Alcohol of 3-C-Ethynyl 1,2- : 5,6-di-O-Isopropylidene-α-D-Allofuranose Derivatives, Tetrahedron, Vol. 47, No. 34, pp. 6975-6982, 1991.
• Y. Fujimoto, T. Eguchi, C. Murasaki, Y. Ohashi, K. Kakinuma, H. Takagaki, M. Abe, K. Inazawa, K. Yamazaki, N. Ikekawa, O. Yoshikawa, T. Ikekawa. Studies on the structure and stereochemistry of cytotoxic furanonaphthoquinones from Tabebuia impetiginosa: 5- and 8-hydroxy-2-(1-hydroxyethyl)naphtho[2,3-b]furan-4,9-diones, J. Chem. Soc., Perkin Trans. 1, No. 10, pp. 2323-2327, 1991.
• Y. Fujimoto, M. Nagakari, Y. Ikuina, N. Ikekawa, K. Kakinuma. Stereochemistry of the hydrogen addition to C-25 of desmosterol by sterol-Δ²⁴-reductase of the silkworm, Bombyx mori, J. Chem. Soc., Chem. Commun., No. 10, pp. 688-689, 1991.
• J. Banerjee, G. Datta, C. P. Dutta, T. Eguchi, Y. Fujimoto, K. Kakinuma. Fern-9(11)-en-25-oic acid, a triterpene from Adiantum venustum, Phytochemistry, Vol. 30, No. 10, pp. 3478-3480, 1991.
• K. Kakinuma, M. Yamagishi, Y. Fujimoto, N. Ikekawa, T. Oshima. Biosynthetic mechanism of sn-2,3-di-O-phytanylglycerol, core membrane lipid of the Archaebacterium Halobacterium halobium, J. Am. Chem. Soc., Vol. 112, No. 7, pp. 2740-2745, Mar. 1990.
• Y. Fujimoto, Y. Ikuina, Y. Kanzawa, M. Nagakari, K. Kakinuma, N. Ikekawa. Mechanism of BF₃・etherate-catalyzed rearrangement of fucosterol epoxide, Heterocycles, Vol. 30, No. 1, pp. 275-278, Jan. 1990.
• KATSUMI KAKINUMA. Biosynthetic Mechanism of ┣DBsn(/)-┫DB-2,3-Di-O-Phytanyl Glycerol, Core Membrane Lipid of the Archaebacterium ┣DBHalobacterium(/)-┫DB ┣DBhalobium(/)-┫DB, Journal of the American Chemical Society, Vol. 112, pp. 7, 1990.
• Y. Fujimoto, C. Murasaki, K. Kakinuma, T. Eguchi, N. Ikekawa, M. Furuya, K. Hirayama, T. Ikekawa, M. Sahai, Y. K. Gupta, A. B. Ray. Squamostatin-A: Unprecedented bis-tetrahydrofuran acetogenin from Annona squamosa, Tetrahedron Lett., Vol. 31, No. 4, pp. 535-538, 1990.
• Y. Fujimoto, Y. Ikuina, M. Nagakari, K. Kakinuma, N. Ikekawa. C-25 Prochirality in the fragmentation reaction catalyzed by fucosterol epoxide lyase from the silkworm, Bombyx mori, J. Chem. Soc., Perkin Trans. 1, No. 7, pp. 2041-2046, 1990.
• Y. Fujimoto, K. Kakinuma, T. Eguchi, N. Ikekawa, N. Hirayama, A. Mbarushimana, D. Ntahomvukiye. 12,15-Dihydroxylabda-8(17),13-dien-19-oic acid from Guizotia scabra, Phytochemistry, Vol. 29, No. 1, pp. 319-321, 1990.
• Y. Ikuina, Y. Kanzawa, Y. Fujimoto, K. Kakinuma. Preparation of (26-¹³C) desmosterol, Chem. Pharm. Bull., Vol. 37, No. 7, pp. 1755-1757, July 1989.
• Y. Fujimoto, M. Hiramoto, K. Kakinuma, N. Ikekawa. Elimination of C-6-hydrogen during the formation of ecdysteroids from cholesterol in Locusta migratoria ovaries, Steroids, Vol. 53, No. 3-5, pp. 477-485, Mar. 1989.
• KATSUMI KAKINUMA. [2,3]-Wittig Rearrangement of Carbohydrate Template. Novel Approach to Chiral Synthesis of 3-Alkylmalic Acids, Tetrahedron Letters, Vol. 30, pp. 31, 1989.
• KATSUMI KAKINUMA. Mechanism and Stereochemistry of the Biosynthesis of 2-Deoxystreptamine and Neosamine C, Journal of Antibiotics, Vol. 42, pp. 6, 1989.
• KATSUMI KAKINUMA. Stereochemistry of Decarboxylation Catalyzed by3-Isopropylmalete Dehydrogenase from The Thermophilic Bacteria ┣DBThermus Thermophilus(/)-┫DB, Journal of the Chemical Society, Chmical Communication, pp. 17, 1989.
• E. Ohnishi, M. Hiramoto, Y. Fujimoto, K. Kakinuma, N. Ikekawa. Isolation and identification of major ecdysteroid conjugates from the ovaries of Bombyx mori, Insect Biochemistry, Vol. 19, No. 1, pp. 95-101, 1989.
• K. Kakinuma, K. Ozawa, Y. Fujimoto, N. Akutsu, T. Oshima. Stereochemistry of the decarboxylation reaction catalyzed by 3-isopropylmalate dehydrogenase from the thermophilic bacterium Thermus thermophilus, J. Chem. Soc., Chem. Commun., No. 17, pp. 1190-1192, 1989.
• Y. Fujimoto, Y. Ikuina, Y. Kanzawa, K. Kakinuma, N. Ikekawa. Mechanism of the boron trifluoride etherate-catalyzed rearrangement of an acyclic trisubstituted epoxide to a carbonyl compound, J. Chem. Soc., Chem. Commun., No. 16, pp. 1107-1109, 1989.
• Y. Fujimoto, Y. Ikuina, K. Kakinuma. Mechanism of the conversion of fucosterol epoxide into desmosterol in insects. Stereochemical fate of the diastereotopic C-26 and C-27 methyl groups of the epoxide, J. Chem. Soc., Chem. Commun., No. 8, pp. 464-466, 1989.
• Y. Fujimoto, T. Eguchi, K. Kakinuma, N. Ikekawa, M. Sahai, Y. K. Gupta. Squamocin, a new cytotoxic bis-tetrahydrofuran containing acetogenin from Annona squamosa, Chem. Pharm. Bull., Vol. 36, No. 12, pp. 4802-4806, Dec. 1988.
• K. Nakamura, T. Yamada, Y. Fujimoto, K. Kakinuma, N. Ikekawa. Synthesis of 3β,6α-dihydroxycholesta-9(11),17(20),24-trien-23-one, the aglycon of acrosome reaction-inducing steroidal saponin Co-ARIS II, Chem. Pharm. Bull., Vol. 36, No. 8, pp. 2808-2812, Aug. 1988.
• T. Eguchi, Y. Fujimoto, K. Kakinuma, N. Ikekawa, M. Sahai, M. P. Verma, Y. K. Gupta. 23-Hydroxyphysalolactone, a new withanolide with a 23-hydroxyl group from Physalis peruviana (Solanaceae), Chem. Pharm. Bull., Vol. 36, No. 8, pp. 2897-2901, Aug. 1988.
• M. Hiramoto, Y. Fujimoto, K. Kakinuma, N. Ikekawa, E. Ohnishi. Ecdysteroid conjugates in the ovaries of the silkworm, Bombyx mori: 3-Phosphates of 2,22-dideoxy-20-hydroxy-ecdysone and of bombycosterol, Experientia, Vol. 44, No. 7, pp. 623-625, July 1988.
• K. Kakinuma, M. Yamaguchi, Y. Fujimoto, T. Oshima, N. Ikekawa. Stereochemistry of the biosynthesis of sn-2,3-O-diphytanyl glycerol, membrane lipid of archaebacteria Halobacterium halobium, J. Am. Chem. Soc., Vol. 110, No. 14, pp. 4861-4863, July 1988.
• T. Kinoshita, M. Miyata, S. M. Ismail, Y. Fujimoto, K. Kakinuma, N. Ikekawa, M. Morisaki. Synthesis and determination of stereochemistry of four diastereoisomers at the C-24 and C-25 position of 3α,7α,12α,24-tetrahydroxy-5β-cholestan-26-oic acid, Chem. Pharm. Bull., Vol. 36, No. 1, pp. 134-141, Jan. 1988.
• Y. Fujimoto, T. Kinoshita, I. Ohya, K. Kakinuma, N. Ikekawa, M. Morisaki. Non-stereoselective conversion of the four diastereomers at the C-24 and C-25 positions of 3α,7α,12α,24-tetrahydroxy-5β-cholestan 26-oic acid into cholic acid, Chem. Pharm. Bull., Vol. 36, No. 1, pp. 142-145, Jan. 1988.
• K. Kakinuma, N. Yamauchi, Y. Fujimoto. Electrophilic reaction on plinol C and syntheses of functionalized 2-oxabicyclo[2.2.1]heptane derivatives, Agricultural and Biological Chemistry, Vol. 52, No. 8, pp. 2049-2057, 1988.
• KATSUMI KAKINUMA. Synthesis of D-(6R)-and D-(6S)-(6- ┣D12┫D1H┣D21┫D2)Glucose, Tetrahedron, Vol. 40, pp. 11, 1984.
• KATSUMI KAKINUMA. Stereochemistry of Ribostamycin Biosynthesis, An Application of ┣D12┫D1H-NMR Spectroscopy, Journal of the American Chemical Society, Vol. 103, pp. 18, 1981.
• KATSUMI KAKINUMA. Structure and Biosynthesis of Setomimycin, A nove 19,9'-Bianthryl Antibiotic, Journal of the American Chemical Society, Vol. 102, pp. 25, 1980.

著書

• 鈴木昭憲, 荒井綜一, 高木正道, 室伏旭, 磯部稔, 柿沼勝己, 他多数. 農芸化学の事典, 朝倉書店, 朝倉書店, pp. 295-300, 2003.
• O. Dannenmuller, K. Arakawa, T. Eguchi, K. Kakinuma, S. Blanc, A.-M. Albrecht, Y. Nakatani, G. Ourisson. Membrane Properties of Archaeal Phospholipids : Effect of Macrocyclization, Giant Vesicles, John Wiley & Sons Ltd., Giant Vesicles, John Wiley & Sons Ltd., pp. 385-390, 1999.
• K. Kakinuma, T. Eguchi. Chirality Transfer on Carbohydrate Template : A Versatile Approach for Chiral Deuterium Labeling, Synthesis and Applications of Isotopically Labelled Compounds 1997, Synthesis and Applications of Isotopically Labelled Compounds 1997, pp. 543-546, 1998.
• KATSUMI KAKINUMA. Mechanistic Enzymology and Molecular Recognition of 3-Isopropylmalate Dehydrogenase Derived from an Extreme Thermophile Thermus thermophilus HB8, KODANSHA : Dynamic Aspects of Natural Products Chemistry, KODANSHA : Dynamic Aspects of Natural Products Chemistry, pp. 187-208, 1997.

特許など

• 柿沼勝己, 工藤史貴, 江口正. ラクタム及びラクトン合成酵素. 特許. 公開. 国立大学法人東京工業大学. 2005/01/27. 特願2005-019886. 2006/08/10. 特開2006-204169. 2006.

学位論文

• 選択的拮抗物質デトキシンの化学構造に関する研究,  本文,  Doctor of Agriculture,  東京大学,  1972/--/--, 

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