論文

• Nobuyuki Akai, Akio Kawai, KAZUHIKO SHIBUYA. Ion-pair structure of vaporized ionic liquid studied by matrix-isolation FTIR spectroscopy with DFT calculation: A case of 1-ethyl-3-methylimidazolium trifluoromethanesulfonate, Vol. 114, p. 12662-12666, Dec. 2010.
• Nobuyuki Akai, Daisuke Wakamatsu, Akio Kawai, KAZUHIKO SHIBUYA. Matrix-isolation infrared spectra of HOOBr and HOBrO produced upon VUV light irradiation of HBr/O2/Ne system, Chemical physics letters, Vol. 499, p. 117-120, Oct. 2010.
• T. Asaka, N. Akai, A. Kawai, K. Shibuya. Photochromism of 3-butyl-1-methyl-2-phenylazoimidazolium in room temperature ionic liquids, Journal of Photochemistry and Photobiology A: Chemistry, Vol. xxx, pp. xxxx, Oct. 2009.
• T.Yoshinobu, N.Akai, A.Kawai, K.Shibuya. Neon matrix-isolation infrared spectrum of measured upon VUV-light irradiation of an HCl/O₂ mixture, Chemical Physics Letters, elsevier, Vol. 477, p. 70-74, July 2009.
• Eiji Furui, Nobuyuki Akai, Akira Ida, Akio Kawai, KAZUHIKO SHIBUYA. Observation of collision-induced near-IR emission of singlet oxygen O₂ a¹∆_g generated by visible light excitation of gaseous O₂ dimol, Chemical Physics Letters, elsevier, Vol. 471, p. 45-49, Mar. 2009.
• Yusuke Miyake, Takehiro Hidemori, Nobuyuki Akai, Akio Kawai, KAZUHIKO SHIBUYA, Shinichi Koguchi, TOMOYA KITAZUME. EPR Study of Rotational Diffusion in Viscous Ionic Liquids: Analysis by a Fractional Stokes–Einstein–Debye Law, Chemistry letters, 日本化学会, Vol. 38, p. 124-125, Feb. 2009.
• Nobuyuki Akai, David Parazs, Akio Kawai, KAZUHIKO SHIBUYA. Cryogenic Neon Matrix-Isolation FTIR Spectroscopy of Evaporated Ionic Liquids: Geometrical Structure of Cation-Anion 1:1 Pair in the Gas Phase, Journal of Physical Chemistry B, ACS, Vol. 113, p. 4756-4762, Feb. 2009.
• Nobuyuki Akai, Akio Kawai, KAZUHIKO SHIBUYA. First Observation of the Matrix-isolated FTIR Spectrum of Vaporized Ionic Liquid: An Example of EmimTFSI, 1-Ethyl-3-methylimidazolium Bis(trifluoromethanesulfonyl)imide, Chemistry Letters, 日本化学会, Vol. 37, No. 3, Page 256, Feb. 2008.
• Akio Kawai, Kazuhiko Shibuya. Charge transfer controlled exchange interaction in radical-triplet encounter pairs as studied by FT-EPR spectroscopy, Journal of Physical Chemistry A, Vol. 111, p. 4890-4901, 2007.
• Masashi Tsuge, Kazuhide Tsuji, Akio Kawai, Kazuhiko Shibuya. Infrared spectroscopy of ozone-water complex in a neon matrix, Journal of Physical Chemistry A, American Cehmical Society, Vol. 111, p. 3540-3547, 2007.
• Masashi Tsuge, Kazuhide Tsuji, Aawai Kawai, Kazuhiko Shibuya. Infrared Spectroscopy of Ozone-Water Complex in a Ne Matrix, Journal of Physical Chemistry A, Vol. 111, pp. 3540-3547, 2007.
• Akio Kawai, Kazuhiko Shibuya. Electron spin dynamics in radical and electronically-excited molecular pair interaction as studied a time-resolved ESR method, Journal of Photochemistry and Photobiology C: Photochemistry Reviews, 7, pp. 89-103, 2006.
• H. Terazono, A. Kawai, K. Tsuji, K. Shibuya. Enhanced intersystem crossing of S₁-T₁ and T₁-S₀ in coronene-galvinoxyl systems as studied by a pulsed ESR method, Journal of Photochemistry and Photobiology A: Chemistry, Vol. 183, pp. 22-30, 2006.
• Akio Kawai, Takehiro Hidemori, Kazuhiko Shibuya. Electron Spin Dynamics of Triplet and Doublet Molecules in Room Temperature Ionic Liquids Studied by A Time-resolved EPR Method, Molecular Physics, Vol. 104, No. 10-11, pp. 1573-1579, 2006.
• Masashi Tsuge, Satoshi Hamatani, Akio Kawai, Kazuhide Tsuji, Kazuhiko Shibuya. Jet Spectroscopy of Arylmethyl Radicals in the Visible Region: Assignment of Low-Frequency Vibrational Modes in Diphenylmethyl and Chlorodiphenylmethl Radicals, Physical Chemistry Chemical Physics, Vol. 8, pp. 256-263, 2006.
• A. Kawai, K. Shibuya. Charge transfer contralled exchange interaction in radical-triplet encounter pairs as studied by FT-EPR Spectroscopy, Journal of Physical Chemistry A, pp. submitted, 2006.
• T. Nakayama, K. Takahashi, Y. Matsumi, K. Shibuya. N(⁴S) Formation following 193.3 nm ArF laser irradiation of NO and NO₂ and its application to kinetic studies of N(⁴S) reactions with NO and NO₂, Journal of Physical Chemistry A, Vol. 109, pp. 10897-10902, 2005.
• T. Isozaki, K. Sakeda, T. Suzuki, T. Ichimura, K. Tsuji, K. Shibuya. Evidence for a non-planar conformer and conformational isomerization of o-fluoroanisole in a low-temperature Ar matrix, Chemical Physics Letters, Vol. 409, No. 1-3, pp. 93-97, 2005.
• M. Ando, S. Yoshiike, T. Suzuki, T. Ichimura, T. Okutsu, M. Ueda, H. Horiuchi, H. Hiratsuka, A. Kawai, K. Shibuya. Evidence of phenoxymethyl radical formation in laser photolyses of anisole in solution, Journal of Photochemistry and Photobiology A: Chemistry, Vol. 174, pp. 194-198, 2005.
• A. Kawai, T. Hidemori, K. Shibuya. Solvation of α-hydroxydiphenylmethyl radical in room temperature ionic liquids studied by transient FT-EPR spectroscopy, Chemical Physics Letters, Vol. 414, No. 4-6, pp. 378-383, 2005.
• J. Zhao, R. Zhang, K. Misawa, K. Shibuya. Experimental product study of the OH-initiated oxidation of m-xylene, Journal of Photochemistry and Photobiology A: Chemistry, Vol. 176, pp. 199-207, 2005.
• S. Toyoda, Naohiro Yoshida, T. Urabe, Y. Nakayama, T. Suzuki, K. Tsuji, KAZUHIKO SHIBUYA, S. Aoki, T. Nakazawa, S. Ishidoya, K. Ishijima, S. Sugawara, 4 other authors. Temporal and latitudinal distributions of stratospheric N₂O isotopomers, Journal of Geophysical Research, Vol. 109, pp. D08308, Apr. 2004.
• Akio Kawai, Takehiro Hidemori, Kazuhiko Shibuya. Polarity of ionic liquid as examined by EPR spectroscopy, Chemstry Letters, Vol. 33, No. 11, pp. 1464-1465, 2004.
• Kazuhide Tsuji, Masashi Ikeda, Junichi Awamura, Akio Kawai, Kazuhiko Shibuya. Vibrational level dependence of lifetime of NO₂ in the D²B₂ state, Chemical Physics Letters, Vol. 374, No. 5/6, pp. 601-607, 2003.
• Akio Kawai, Yasuyuki Watanabe, Kazuhiko Shibuya. Control of ferromagnetic and antiferromagnetic couplings in a galvinoxyl-triplet chrysene encounter complex through solvent polarity, Chemical Physics Letters, Vol. 372, No. 1, pp. 8-14, 2003.
• Satoshi Hamatani, Kazuhide Tsuji, Akio Kawai, Kazuhiko Shibuya. Dispersed Fluorescence Spectra of Jet-Cooled Benzophenone Ketyl Radical: Assignment of the Low-Frequency Vibrational Modes, Physical Chemistry and Chemical Physics, Vol. 5, No. 7, pp. 1370-1375, 2003.
• Akio Kawai, Hironao Tanaka, Yoshiki Nakashima, Toshifumi Iimori, Kazuhide Tsuji, Kinichi Obi, Kazuhiko Shibuya. Protonation and multi-hydrogenation of benzophenone (BP) in BP/toluene and BP/ethanol binary cation clusters, Chemical Physics Letters, Vol. 381, No. 3/4, pp. 354-361, 2003.
• Takashi Imamura, Hidekazu Chono, Kazuhiko Shibuya, Nobuaki Washida. Rate Coefficient for the Reaction of CCl₃ Radicals with Ozone, International Journal of Chemical Kinetics, Vol. 35, pp. 310-316, 2003.
• Kazuhide Tsuji, Naoko Arakawa, Akio Kawai, Kazuhiko Shibuya. Spectroscopy and Predissociation of Acetylene in the np Gerade Rydberg States, Journal of Physical Chemistry A, Vol. 106, No. 5, pp. 747-753, 2002.
• Akio Kawai, Yasuyuki Watanabe, Kazuhiko Shibuya. Time resolved ESR study on energy splitting of quartet and doublet states in radical-triplet encounter pairs, Molecular Physics, Vol. 100, No. 8, pp. 1225-1234, 2002.
• Satoshi Hamatani, Kazuhide Tsuji, Akio Kawai, Kazuhiko Shibuya. Laser Induced Fluorescence, Dispersed Emission, and Lifetime Measurements of Jet-Cooled Chloro-Substituted Benzyl Radicals, Chemical Physics Letters, Vol. 360, No. 5-6, pp. 466-472, 2002.
• Akio Kawai, Kazuhiko Shibuya. Energy separation between quartet and doublet spin states of radical-triplet molecule pairs; unusual ferromagnetic interaction in a 1,1-diphenyl-2-picrylhydrazyl and triplet coronene system, Journal of Physical Chemistry A, Vol. 106, pp. 000-000, 2002.
• Akio Kawai, Takashi Fuse, Kazuhiko Shibuya. Quenching of singlet molecular oxygen (¹Δ_g) by vitamins and polyphenols studied by time-resolved ESR, EPR in the 21st century: Basics and Applications to Material, Life and Earth Sciences (Elsevier), pp. 349-354, 2002.
• Akio Kawai, Makoto Hirakawa, Toyohiko Abe, Kinichi Obi, Kazuhiko Shibuya. Specific Solvent Effect on the Structure and Reaction Dynamics of Benzophenone Ketyl Radical, Journal of Physical Chemistry A, Vol. 105, No. 42, pp. 9628-9636, 2001.
• Kosuke Aiuchi, Kazuhiko Shibuya. The Electronic Spectrum of Jet-Cooled FeC in the Visible Region, Journal of Molecular Spectroscopy, Vol. 209, No. 1, pp. 92-104, 2001.
• Kazuhide Tsuji, Kiyoshi Nakata, Hiromasa Oishi, Kazuhiko Shibuya. An OH Monitoring Method Using Infrared-Ultraviolet Double Resonance Laser Induced Fluorescence, Bulletin of the Chemical Society of Japan, Vol. 73, No. 12, pp. 2695-2702, 2000.
• A. Kawai, K. Shibuya, K. Obi. Effect of Charge Transfer State on the Exchange Interaction of Radical-Triplet Encounter Pairs, Appl. Magn. Reson., Vol. 18, pp. 343-350, 2000.
• S. Kudoh, T. Uechi, M. Takayanagi, M. Nakata, N. Tanaka, K. Shibuya. Infrared spectra of dimethylaminomethanol in low-temperature argon matrices and conformational analysis of DFT calculation, J. Mol. Struct., Vol. 524, pp. 251-258, 2000.
• K. Aiuchi, K. Tsuji, K. Shibuya. The low-lying electronic state of FeC observed 3460 cm^-1 above X ³Δ₂, Chem. Phys. Letters, Vol. 309, No. 3-4, pp. 229-233, 1999.
• KAZUHIKO SHIBUYA. Electronic spectroscopy and predissociation mechanism of Ar-NO in the 3p Rydberg states, Chem. Phys., Vol. 231, pp. 279-288, 1998.
• N. K. Shrestha, E. J. Yagi, Y. Takatori, A. Kawai, Y. Kajii, K. Shibuya, K. Obi. Photochemical α-Cleavage Reaction of Benzoin and Its Derivatives, J. Photochem. Photobio. A: Chem., Vol. 116, pp. 179-185, 1998.
• K. Takeda, Y. Kajii, K. Shibuya, K. Obi. Heats of Formation of Transient Radicals in Solution, J. Photochem. Photobio. A : Chem., Vol. 115, pp. 109-115, 1998.
• K. Aoki, K. Hoshina, K. Shibuya. Vibronic analysis of fluorescence spectrum of NO┣D22┫D2D┣D12┫D1B┣D22┫D2(0,0,0) in the region of 250-550nm, The Journal of Chemical Physics, Vol. 105, No. 6, pp. 2228-2235, 1996.
• K. Takeda, Y. Kajii, K. Shibuya. Kinetic Studies on Photochemical of C┣D260┫D2 with Amine in Solution, J. Photobio. A : Chem, Vol. 92, pp. 69-72, 1995.
• M. Akiike, K. Tsuji, K. Shibuya, K. Obi. van der Waals Vibration of NO-methane Complexes in the A┣D12┫D1Σ-X┣D12┫D1Πstate, Chem. Phys. Letters, Vol. 243, pp. 89-93, 1995.
• K. Tsuji, K. Shibuya, K. Obi. Intermolecular Vibrations of the complex of NO in the ns σRydberg States and Ar, Laser Chem., Vol. 15, No. 2-4, pp. 157-165, 1995.
• K. Shibuya, T. Kusumoto, H. Nagai. Optical-optical double resonance spectroscopy of NO┣D22┫D2 in the 590.1 nm region, Laser Chem., Vol. 14, No. 1-3, pp. 119-129, 1994.
• Y. Takatori, Y. Kajii, K. Shibuya, K. Obi. Dissociation of Highly Excited Triplet Benzophenone into Phenyl Radicals and Carbon Monooxide : Determination of the Reaction Quantum Yield and Heat of Reaction by Time-Resolved Thermal Lensing Technique, Chem. Phys., Vol. 180, No. 1, pp. 99-107, 1994.
• Y. Kajii, K. Takeda, K. Shibuya. Photochemical reaction of C┣D260┫D2 in the presence of triethylamine in toluene, Chem. Phys. Lett., Vol. 204, No. 3, pp. 4,283-286, 1993.
• N. Tanaka, Y. Kajii, K. Shibuya, M. Nakata. Visible-Light-Induced Reaction of NO┣D22┫D2 with Conjugated Dienes in a Low-Temperature Ar Matrix, J. Phys. Chem., Vol. 97, No. 27, pp. 7048-7053, 1993.
• T. Suzuki, Y. Kajii, K. Shibuya, K. Obi. Relaxation processes of highly excited naphthalene in solution studied by time-resolved thermal lensing technique, Chemical Physics, Vol. 161, pp. 447-452, 1992.
• Y. Kajii, H. Itabashi, K. Shibuya, K. Obi. Complex Formation of Benzophenone Ketyl Radical and Trimethylamine, Journal of Physical Chemistry, Vol. 96, No. 18, pp. 7244-7247, 1992.
• T. Suzuki, Y. Kajii, K. Shibuya, K. Obi. Photocyclization of Diphenylamine Studied by Time-Resolved Thermal Lensing. Heat of Reaction, Energetics, and Reactivity of Intermediates, Bulletin of the Chemical Society of Japan, Vol. 65, No. 4, pp. 1084-1088, 1992.
• Y. Kajii, T. Suzuki, Y. Takatori, K. Shibuya, K. Obi. Photodissociation of Highly-Excited Triplet State of Benzophenone Studied by a Time-Resolved Thermal Lensing Technoque, Bulletin of the Chemical Society of Japan, Vol. 65, pp. 1349-1355, 1992.
• T. Suzuki, Y. Kajii, K. Shibuya, K. Obi. Calorimetric Standards for Photothermal Methods in Ultraviolet and Visible Spectral Regions, Research on Chemical Intermediates, Vol. 15, pp. 261-270, 1991.

著書

• 渋谷一彦, 辻和秀, 河合明雄. 改訂第5版 化学便覧 基礎編Ⅱ 12.化学反応, 丸善, 丸善, 2004.
• 渋谷一彦. 続・身近な地球環境－酸性雨を考える－「分子科学からみたOHラジカル」, コロナ社, コロナ社, 2002.
• 小尾欣一, 渋谷一彦. 基礎量子化学, 化学同人 , 化学同人 , 2002.
• 渋谷一彦. 光と化学の事典, 丸善, 丸善, 2001.
• 渋谷一彦. 超高速化学反応, 化学と教育, 化学と教育, Vol. 48, No. 3, pp. 166-169, 2000.
• 渋谷一彦, 辻和秀. 総説 ファンデルワールス分子の励起状態ダイナミクス, 分光研究, 分光研究, Vol. 48, No. 5, pp. 193-206, 1999.
• 辻和秀, 渋谷一彦. フリーラジカルの科学（分担）, 学会出版センター, 学会出版センター, 1998.
• 小尾欣一, 渋谷一彦. 実験化学講座11. 反応と速度（分担）, 丸善, 丸善, 1993.
• 小尾欣一, 八嶋建明, 柿沼勝巳, 神宮寺守, 渋谷一彦. ピメンテル 市民の化学－今日そしてその未来－（共訳）, 東京化学同人, 東京化学同人, 1990.

国際会議発表 (査読有り)

• Masaharu Fujitake, Aki Toba, Masaya Mori, Fuyuki Miyazawa, Nobukimi Ohashi, Kosuke Aiuchi, Kazuhiko Shibuya. Near Infrared Diode Laser Spectroscopy of FeC in the 0.8 μm Region: A Simultaneous Analysis of the X³Δ_i and [3.8]¹Δ States, Journal of Molecular Spectroscopy, Vol. 208, No. 2, pp. 253-270, 2001.
• K. Aiuchi, K. Shibuya. Jet-cooled optical spectroscopy of FeN between 16300 and 21600 cm^-1, Journal of Molecular Spectroscopy, Vol. 204, No. 2, pp. 235-261, 2000.
• K. Tsuji, C. Terauchi, S. Tsuchiya, K. Shibuya. Trans-cis isomerization of acetylene in the A¹A_u state as studied by dispersed fluorescence spectroscopy, Chem. Phys. Letters, Vol. 306, No. 1-2, pp. 41-47, 1999.
• T. Abe, A. Kawai, Y. Kajii, K. Shibuya, K. Obi. Solvent Effects on the Complex Formation of Benzophenone Ketyl Radical and Triethylamine, Journal of Physcal Chemistry A, Vol. 103, No. 11, pp. 1457-1462, 1999.
• N. Tanaka, J. Oike, K. Shibuya, S. Kudoh, M. Nakata. Visible Light Induced Oxygen Atom Transfer from NO₂ to (CH₃)₃N a Cryogenic Ar Matrix, Rev. Chem. Intermedi. 24[8], 893-903 (1998), Vol. 24, No. 8, pp. 893-903, 1998.
• K. Shibuya, S. Suzuki, T. Imamura, I. Koyano. Dissociation of State Selected NO₂⁺ Ions Studied by Threshold Photoelectron-Photoion Coincidence Techniques in the Region of 40-100nm, Journal of Physics and Chemistry A, Vol. 101, No. 4, pp. 685-689, 1997.
• K. Shibuya, C. Terauchi, M. Sugawara, K. Tsuji, K. Aoki, S. Tsuchiya. Vibrational level structure of NO₂ C²A₂ in the energy region of 16200-21000cm_-1: Evidence for the breakdown of C_2v symmetry, Journal of Molecular Structure, Vol. 413-414, pp. 501-509, 1997.
• N. Tanaka, M. Nakata, K. Shibuya. Photoinduced Dehydrogenation of 1,4-Cyclohexadiene by NO₂ in a Crvogenic Ar Matrix, Journal of Photochemistry and Photobiology A : Chemistry, Vol. 106, pp. 113-118, 1997.
• M. Nakata, Y. Somura, M. Takayanagi, N. Tanaka, K. Shibuya. Visible Light Induced Reaction of NO₂ with Propene in Low-Temperature Argon and Xenon Matrices, Journal of Physical Chemstry, Vol. 100, No. 39, pp. 15815-15820, 1996.
• N. Tanaka, J. Oike, K. Shibuya, M. Nakata. Visible Light Induced Oxygen Atom Transfer from NO₂ to (CH₃)₂NH in a Cryogenic Ar Matrix, Journal of Physical Chemstry, Vol. 100, pp. 4873-4878, 1996.
• N. Tanaka, J. Oike, Y. Kajii, K. Shibuya, M. Nakata. Photoinduced dehydrogenation reaction of CH₃NH₂ by NO₂ in a cryogenic Ar matrix : Identification of CH₂=NH…H₂O complex, Chemical Physics Letters, Vol. 232, No. 1,2, pp. 109-114, 1995.
• K. Tsuji, K. Shibuya, K. Obi. Bound-Bound A²Σ⁺-X²Π transition of NO-Ar van der Waals Complexes, Journal of Chemical Physics, Vol. 100, No. 8, pp. 5441-5447, 1994.
• K. Aoki, H. Nagai, K. Hoshina, K. Shibuya. Rotational Quantum Number and Vibronic Symmetry of NO₂ Excited with Visible Light in the Region of 563-566 nm : Optical-Optical Double Resonance Measurement and Spin-Orbit Interaction between ²B₂ and C²A₂ States, Journal of Physical Chemistry, Vol. 97, No. 35, pp. 8889-8894, 1993.
• K. Tsuji, 渋谷 一彦, K. Obi. 共鳴多光子イオン化法を利用したNO(E²Σ⁺)-Ar錯体の分光学的研究, 分光研究, Vol. 42, No. 6, pp. 385-391, 1993.
• Y. Takatori, T. Suzuki, Y. Kajii, K. Shibuya, K. Obi. Highly Excited Triplet State Dynamics of Benzophenone Studied by Pump and Probe Time-Resolved Thermal Lensing Spectroscopy, Chemical Physics, Vol. 169, No. 2, pp. 291-296, 1993.
• W. Sisk, H. Endo, K. Shibuya, K. Obi. NO A²Σ⁺-X²Π Chemiluminescence Produced from the Reaction of Excited NO₂ with Acetylene and Its Derivatives in Their Triplet States, J. Phys. Chem., Vol. 96, pp. 16, 1992.
• Y. Kajii, T. Nakagawa, S. Suzuki, Y. Achiba, K. Obi, K. Shibuya. Transient absorption, lifetime and relaxation of C₆₀ in the triplet state, Chemical Physics Letters, Vol. 181, No. 2,3, pp. 100-104, 1991.
• K. Shibuya, T. Kusumoto, H. Nagai, K. Obi. Possible Rotationally Resolved Detection of NO₂ in the C²A₂ State by Optical-Optical Double Resonance Spectroscopy, Journal of Chemical Physics, Vol. 95, No. 1, pp. 720-721, 1991.
• K. Shibuya, T. Kusumoto, H. Nagai, K. Obi. SpinーOrbitーInduced and SymmetryーForbidden C²A₁ Absorption of NO₂ Using OpticalーOptical DoubleーResonance Spectroscopy in the 588-591-nm Range, Journal of Physical Chemistry, Vol. 95, No. 1, pp. 720-721, 1991.
• KAZUHIKO SHIBUYA. Optical-optical double resonance of NO₂ in the region of 612-614 nm : The role of ²A₁ vibronic levels as dark and perturbing state, Journal of Chemical Physics, Vol. 93, pp. 11, 1990.
• KAZUHIKO SHIBUYA. Vibronic Excitation of Oxygen-Atom Transfer form NO₂ to Ethylene by Long-Wavelength Visible Light in a Cryogenic Matrix, Journal of Physcical Chemistry, Vol. 94, pp. 21, 1990.

学位論文

• Photochemical Studies of Methylene and Formyl Radicals in the Gas Phase,  Thesis,  Doctor of Science,  Tokyo Institute of Technology,  1976/03/26,    (学位授与組織:東京工業大学大学院理学研究科)
• Vacuum Ultraviolet Photolysis of Cyclopropane,  Master of Science,  東京工業大学大学院理学研究科,  1973/--/--, 

[ BibTeX 形式で保存 ]    [ 論文・著書をCSV形式で保存 ]    [ 特許をCSV形式で保存 ]