論文

• Kohsuke Aikawa, Koichi Mikami. Dual Chirality Control of Palladium(II) Complexes Bearing Tropos Biphenyl Diamine Ligands, Chem. Commun., pp. 5799-5801, 2005.
• K. Mikami, S. Kataoka, K. Aikawa. Tropos or Atropos Nature of Rhodium Complexes Bearing a Tetrakis(phosphanyl)terphenyl Ligand: Highly Enantioselective Catalysis of Ene-Type Cyclization, Org. Lett., Vol. 7, No. 26, pp. 5777-5780, 2005.
• K. Mikami, K. Wakabayashi, K. Aikawa. “Achiral” Benzophenone Ligand for Highly Enantioselective Ru-Catalysts in Ketone Hydrogenation, Org. Lett., Vol. 8, No. 8, pp. 1517-1519, 2006.
• Koichi Mikami, Kazuki Wakabayashi, Yukinori Yusa, Kohsuke Aikawa. Achiral Benzophenone Ligand with Chiral Diamine Activator for High Enantiocontrol, Chem. Commun., pp. 2365-2367, June 2006.
• Koichi MIKAMI, Kohsuke AIKAWA, Masahiro Yamanaka. Negative nonlinear effect in aquo palladium catalysis depending on tropos biphenylphosphine ligand chirality controlled by chiral diaminobinaphthyl activator, Pure and Applied Chem., Vol. 76, No. 3, pp. 537-540, 2004.
• Koichi Mikami, Yukinori Yusa, Manabu Hatano, Kazuki Wakabayashi, Kohsuke Aikawa. Highly enantioselective spiro cyclization of 1,6-enynes catalyzed by cationic skewphos rhodium(I) complex, Chem. Commun., No. 1, pp. 98-99, 2004.
• K. Mikami, Y. Yusa, K. Aikawa, M. Hatano. Molecular design of DABNTf as a highly efficient resolving reagent for racemic Pd complex with tropos biphenylphosphine (BIPHEP) ligand: circular dichroism (CD) spectra of enantiopure BIPHEP-Pd complex, Chirality, Vol. 15, No. 1, pp. 105-107, 2003.
• Koichi Mikami, Kohsuke Aikawa, Yukinori Yusa. Asymmetric Activation of the Pd Catalyst Bearing the Tropos Biphenylphosphine (BIPHEP) Ligand with the Chiral Diaminobinaphthyl (DABN) Activator, Org. Lett., Vol. 4, No. 1, pp. 95-97, Jan. 2002.
• Koichi Mikami, Kohsuke Aikawa, Yukinori Yusa, Manabu Hatano. Resolution of Pd Catalyst with Tropos Biphenylphosphine (BIPHEP) Ligand by DM-DABN: Asymmetric Catalysis by an Eantiopure BIPHEP-Pd Complex, Org. Lett., Vol. 4, No. 1, pp. 91-94, 2002.
• Toshinobu Korenaga, Kohsuke Aikawa, Masahiro Terada, Susumu Kawauchi, Koichi Mikami. Dynamic Chirality Control of (Xyl-)BIPHEP Ligands Leading to their Diastereo- merically Pure Ru Complexes with a Chiral N-Substituted DPEN, Adv. Synth. Catal., Vol. 343, pp. 284-288, 2001.
• Koichi Mikami, Kohsuke Aikawa, Toshinobu Korenaga. General Synthetic Route to Chiral Flexible Biphenylphosphine Ligands: The use of a Chiral Additive Enables the Preparation and Observation of Metal Complexes Incorporating the Enantiopure Form, Org. Lett., Vol. 3, pp. 243-245, 2001.
• Jun Mihara, Kohsuke Aikawa, Tatsuya Uchida, Ryo Irie, Tsutomu Katsuki. LEWIS ACID CATALYSIS OF SECOND-GENERATION METALLOSALEN COMPLEXES: AN EXPLANATION FOR STEREOCHEMISTRY OF ASYMMET- RIC HETERO DIELS-ALDER REACTION, Heterocycles, Vol. 54, pp. 395-404, 2001.
• Kohsuke Aikawa, Ryo Irie, Tsutomu Katsuki. Asymmetric hetero Diels-Alder reaction using chiral cationic metallosalen complexes as catalysts, Tetrahedron, Vol. 57, pp. 845-851, 2001.
• Koji Kadota, Toshiki Mikami, Ai Kohata, Jumpei Morimoto, Shinsuke Sando, Kohsuke Aikawa, Takashi Okazoe. Synthesis of Short Peptides with Perfluoroalkyl Side Chains and Evaluation of Their Cellular Uptake Efficiency, July 2023.
• Shigekazu Ito, Masaki Nanko, Tomokazu Shinozaki, Masafumi Kojima, Kohsuke AIKAWA, KOICHI MIKAMI. Dynamic Chirality Control of tropos DPCB-digold Skeleton by Chiral Binaphthyldicarboxylate, Chem. Asian J., Wiley, Vol. 11, no. 6, pp. 823-827, Mar. 2016.
• Kohsuke Aikawa, Yuzo Nakamura, Yuki Yokota, Wataru Toya, Koichi Mikami. Stable but Reactive Perfluoroalkylzinc Reagents: Application to Ligand-Free Copper-Catalyzed Perfluoroalkylation of Aryl Iodides, Chem. Eur. J., Vol. 21, No. 1, pp. 96-100, Jan. 2015.
• Kohsuke Aikawa, Yuya Asai, Yūta Hioki, Koichi Mikami. Catalytic and highly enantioselective Friedel-Crafts type reactions of heteroaromatic compounds with trifluoropyruvate and glyoxylate by a dicationic palladium complex, Tetrahedron: Asymmetry, Vol. 25, No. 15, pp. 1104-1115, July 2014.
• Hiroki Serizawa, Kohsuke Aikawa, Koichi Mikami. Direct Synthesis of Pentafluoroethyl Copper from Pentafluoropropionate as an Economical C2F5 Source: Application to Pentafluoroethylation of Arylboronic Acids and Aryl Bromides, Org. Lett., Vol. 16, No. 13, pp. 3456-3459, June 2014.
• Ryota Hashimoto, Toshiaki Iida, Kohsuke AIKAWA, Shigekazu Ito, KOICHI MIKAMI. Direct alpha-Siladifluoromethylation of Lithium Enolates with Ruppert-Prakash Reagent via C-F Bond Activation, Chem. Eur. J., Vol. 20, No. 10, pp. 2750-2754, May 2014.
• Motohiro Fujiu, Ryota Hashimoto, Yuzo Nakamura, Kohsuke AIKAWA, Shigekazu Ito, KOICHI MIKAMI. Paradigm Shift from Alkaline (Earth) Metals to Early Transition Metals in Metalorganofluorine Chemistry: Perfluoroalkyl Titanocene(III) Reagents in situ Prepared via Not Titanocene(II) but Titanocene(III) Species, Chem. Eur. J., Vol. 20, No. 8, pp. 2382-2386, Apr. 2014.
• Kohsuke Aikawa, Natsumi Shimizu, Kazuya Honda, Yūta Hioki, Koichi Mikami. Effect of the trifluoromethyl group on torquoselectivity in the 4π ring-opening reaction of oxetenes: stereoselective synthesis of tetrasubstituted olefins, Chem. Sci., Vol. 5, No. 1, pp. 410-415, Jan. 2014.
• Hiroki Serizawa, Kohsuke Aikawa, Koichi Mikami. Direct Synthesis of a Trifluoromethyl Copper Reagent from Trifluoromethyl Ketones: Application to Trifluoromethylation, Chem. Eur. J., Vol. 19, No. 52, pp. 17692-17697, Dec. 2013.
• Yuzo Nakamura, Motohiro Fujiu, Tatsuya Murase, Yoshimitsu Itoh, Hiroki Serizawa, Kohsuke Aikawa, Koichi Mikami. Cu-catalyzed trifluoromethylation of aryl iodides with trifluoromethylzinc reagent prepared in situ from trifluoromethyl iodide, Beilstein J. Org. Chem., Vol. 9, pp. 2404-2409, Sept. 2013.
• Motohiro Fujiu, Yuzo Nakamura, Hiroki Serizawa, Kohsuke AIKAWA, Shigekazu Ito, KOICHI MIKAMI. Direct Preparation of Trifluoromethylindium Reagents from Trifluoromethyl Iodide: Effective Trifluoromethylation and Perfluoroalkylation Reagents, Eur. J. Org. Chem., Vol. 36, pp. 7043-7047, Nov. 2012.
• Toshiaki Iida, Ryota Hashimoto, Kohsuke AIKAWA, Shigekazu Ito, KOICHI MIKAMI. Umpolung of Fluoroform by C-F Bond Activation: Direct Difluoromethylation of Lithium Enolates, Angew. Chem. Int. Ed., Vol. 51, No. 38, pp. 9535-9538, Aug. 2012.  公式リンク  
  
• Kohsuke Aikawa, Tatsuya Okamoto, Koichi Mikami. Copper(I)-Catalyzed Asymmetric Desymmetrization: Synthesis of Five-Membered-Ring Compounds Containing All-Carbon Quaternary Stereocenters, J. Am. Chem. Soc., Vol. 134, No. 25, pp. 10329-10332, June 2012.
• Kohsuke Aikawa, Yoshitaka Miyazaki, Koichi Mikami. Stable Axial Chirality in Metal Complexes Bearing 4,4’-Substituted BIPHEPs: Application to Catalytic Asymmetric Carbon-Carbon Bond-Forming Reactions, Bull. Chem. Soc. Jpn., Vol. 85, No. 2, pp. 201-208, Feb. 2012.
• Kohsuke Aikawa, Yūta Hioki, Natsumi Shimizu, Koichi Mikami. Catalytic Asymmetric Synthesis of Stable Oxetenes via Lewis Acid-promoted [2 + 2] Cycloaddition, J. Am. Chem. Soc., Vol. 133, No. 50, pp. 20092-20095, Nov. 2011.
• Koichi Mikami, Kohsuke Aikawa, Junpei Aida. Fragment-Based Reaction Discovery of Non-Ene-Type Carbon-Carbon Bond-Forming Reactions: Catalytic Asymmetric Oxetane Synthesis by Screening Olefinic Reactants without Allylic Hydrogen, Synlett, No. 18, pp. 2719-2724, Sept. 2011.
• Kohsuke Aikawa, Kazuya Honda, Shunsuke Mimura, Koichi Mikami. Highly enantioselective Friedel-Crafts alkylation of indole and pyrrole with beta,gamma-unsaturated alpha-ketoester catalyzed by chiral dicationic palladium complex, Tetrahedron Lett., Vol. 52, No. 50, pp. 6682-6686, July 2011.
• Kohsuke Aikawa, Shunsuke Mimura, Yukinobu Numata, Koichi Mikami. Palladium-Catalyzed Enantioselective Ene and Aldol Reactions with Isatins, Keto Esters, and Diketones: Reliable Approach to Chiral Tertiary Alcohols, Eur. J. Org. Chem., No. 1, pp. 62-65, Jan. 2011.
• Kohsuke Aikawa, Masafumi Kojima, Koichi Mikami. Synergistic Effect: Hydroalkoxylation of Allenes through Combination of Enantiopure BIPHEP-Gold Complexes and Chiral Anions, Advanced Synthesis & Catalysis, WILEY, Vol. 352, no. 18, pp. 3131-3135, Dec. 2010.
• Kohsuke Aikawa, Yuta Hioki, KOICHI MIKAMI. Highly Enantioselective Alkynylation of Trifluoropyruvate with Alkynylsilanes Catalyzed by the BINAP-Pd Complex: Access to alpha-Trifluoromethyl-Substituted Tertiary Alcohols, Organic Letters, ACS Publications, Vol. 12, no. 24, pp. 5716-5719, Nov. 2010.
• Kohsuke Aikawa, Yuta Hioki, KOICHI MIKAMI. Catalytic Enantioselective Arylation of Glyoxylate with Arylsilanes: Practical Synthesis of Optically Active Mandelic Acid Derivatives, Chemistry – An Asian Journal, WILEY, Vol. 5, no. 11, pp. 2346-2350, Nov. 2010.
• Kohsuke Aikawa, Yuta Hioki, KOICHI MIKAMI. Highly Enantioselective Alkenylation of Glyoxylate with Vinylsilane Catalyzedby Chiral Dicationic Palladium(II) Complexes, J. Am. Chem. Soc., ACS Publications, Vol. 131, no. 39, pp. 13922–13923, Sept. 2009.
• K. Aikawa, M. Kojima, K. Mikami. Axial Chirality Control of Gold(biphep) Complexes by Chiral Anions: Application to Asymmetric Catalysis, Angew. Chem. Int. Ed., WILEY, Vol. 48, no. 33, pp. 6073–6077, Aug. 2009.
• Kazuki Wakabayashi, Kohsuke Aikawa, Koichi Mikami. Chirality Control of Tropos Diphenylmethane-derived Phosphoramidites by Chiral Dienes: Its Application to Asymmetric Michael Addition, Heterocycles, Vol. 77 (Special issue for Prof. K. Fukumoto), no. 2, pp. 927-943, 2009.
• Kazuki WAKABAYASHI, Kohsuke AIKAWA, Susumu KAWAUCHI, Koichi MIKAMI. Catalyst Self-Adaptation in Conjugate Addition to Nitroalkenes and Nitroacrylates: Instant Chirality Control in Diphenylmethane-Based Phosphoramidite Ligands, J. Am. Chem. Soc., vol. 130, no. 15, pp. 5012-5013, Apr. 2008.
• Kazuki WAKABAYASHI, Kohsuke AIKAWA, Y.Takabayashi, Susumu KAWAUCHI, Koichi MIKAMI. Axial Chirality Control of tropos BIPHEP—Rh Complexes by Chiral Dienes: Synergy Effect in Catalytic Asymmetric Hydrogenation, Chem. Commun, vol. 41, pp. 5095-5097, 2008.
• Kazuki Wakabayashi, Kohsuke Aikawa, Koichi Mikami. Benzophenone-Derived Catalyst with Self-Adaptation: Highly Enantioselective Hydrogenation Irrespective of Ketone Substrates, Heterocycles, Vol. 76(Special issue for Prof. R. Noyori), no. 2, pp. 1525-1535, 2008.
• Kohsuke AIKAWA, Isao KAITO, Koichi MIKAMI. Enantiofacial Control of Planar Chiral Arene Ru Complexes Bearing Tropos Biphenyl Ligands, Chem. Lett., vol. 36, no. 12, pp. 1482-1483, Dec. 2007.
• Koichi MIKAMI, Yuji KAWAKAMI, Katsuhiro AKIYAMA, Kohsuke AIKAWA. Enantioselective Catalysis of Ketoester-Ene Reaction of Silyl Enol Ether to Construct Quaternary Carbons by Chiral Dicationic Palladium(II) Complexes, J. Am. Chem. Soc., vol. 129, no. 43, pp. 12950-12951, Sept. 2007.
• F. Saitoh, H. Nishida, T. Mukaihira, Kohsuke AIKAWA, KOICHI MIKAMI. Dynamic Kinetic Resolution for the Catalytic Asymmetric Total Synthesis of Antithrombotic Agents M58163 and M58169, Adv. Synth. Cat., vol. 349, no. 4-5, p. 617–628, Feb. 2007.
• Saitoh, F.; Nishida, H.; Mukaihira, K. Aikawa, K. Mikami. Asymmetric Synthesis of Antithrombotic Agents M58163 and M58169: Dynamic Kinetic Resduction in Amide Formation Catalyzed by La-Linked BINOL Complex, Eur. J. Org. Chem, vol. 2006, no. 24, pp. 5454-5457, Dec. 2006.
• Kohsuke Aikawa, Susumu Akutagawa, Koichi Mikami. Asymmetric Synergy between Chiral Dienes and Diphosphines in Cationic Rh(I)-Catalyzed Intramolecular [4+2]Cycloaddition, J. Am. Chem. Soc., Vol. 128, No. 39, pp. 12648-12649, Oct. 2006.
• F. Saitoh, H. Nishida, T. Mukaihira, K. Aikawa, K. Mikami. Asymmetric Synthesis of Antithrombotic Agent M55529: The First Enantioselective Cyclic N,O-Acetal Formation, Eur. J. Org. Chem., Vol. 2006, No. 10, pp. 2269-2272, May 2006.
• Koichi Mikami, Shohei Kataoka, Kazuki Wakabayashi, Kohsuke Aikawa. Chiral Aminoalcohol NOBIN for Instantaneous Chirality Control of Racemic but Tropos BIPHEP-Rh(I)-Complexes: Highly Enantioselective Ene-Type Cyclization of 1,6-Enynes Catalyzed by Rh(I)-Complexes without Use of Acid, Tetrahedron Lett., Vol. 47, pp. 6361-6364, 2006.
• Koichi Mikami, Hitomi Kakuno, Kohsuke Aikawa. Enantiodiscrimination and Enantioontrol of Neutral and Cationic PtII Complexes Bearing the Tropos Biphep Ligand: Application to Asymmetric Lewis Acid Catalysis, Angew. Chem. Int. Ed., Vol. 44, pp. 7257-7260, Jan. 2005.
• Yuko Matsuoka, Kohsuke Aikawa, Ryo Irie, Tsutomu Katsuki. Asymmetric synthesis of cryptofolione and determination of its absolute configuration, Heterocycles, No. 66, pp. 187-194, 2005.
• Kohsuke Aikawa, Satoshi Kainuma, Manabu Hatano, Koichi Mikami. Asymmetric Catalysis of Ene Reactions with Trifluoropyruvate Catalyzed by Dicationic Palladium(II) Complexes, Tetrahedron Lett., Vol. 45, No. 1, pp. 183-185, 2004.
• K. Mikami, Y. Yusa, M. Hatano, K. Wakabayashi, K. Aikawa. Enantioselective sipro ene-carbocyclization of 1,6-enynes catalyzed by tropos skewphos rhodium(Ⅰ) compxes, Tetrahedron: Symposia-in-Print, vol. 60, pp. 4475-4480, 2004.
• K. Mikami, S. Kainura, Y. Kawakami, K. Aikawa, T. Saito, N. Sayo, H. Kumabayashi. Enantioselective Catalysis of Carbonyl-Ene and Friedel-Crafts Reactions with Trifluoropyruvate by "Naked" Dicationic Palladium(Ⅱ) Complexes with SEGPHOS Ligands, Tetrahedron: Asymmetry, Vol. 15, pp. 3885-3889, 2004.
• Kohsuke Aikawa, Koichi Mikami. Helical chirality control of palladium complexes that bear a tetrakis(phosphanyl)terphenyl ligand:as asymmetric lewis acid catalysts, Angew. Chem. Int. Ed., Vol. 42, No. 44, pp. 5458-5461, Oct. 2003.
• Kohsuke Aikawa, Koichi Mikami. Atropos but Achiral Tris(phosphanyl)biphenyl Ligands for Ru-Catalyzed Asymmetric Hydrogenation, Angew. Chem. Int. Ed., Vol. 42, No. 44, pp. 5455-5258, Oct. 2003.
• Koichi Mikami, Kohsuke Aikawa. Dynamic Asymmetric Catalysis by Diphenylphosphinoferrocene (DPPF)-Nickel Complexes through Control of Axial Chirality by Chiral Diamines, Org. Lett., Vol. 4, No. 1, pp. 99-101, Jan. 2002.
• Jian Hao, Sonia Taktak, Kohsuke Aikawa, Yukinori Yusa, Manabu Hatano, Koichi Mikami. Biphenylphosphine-Palladium(II) Complexes-Catalyzed Friedel-Crafts Reaction for the Synthesis of alpha-Amino and alpha-Hydroxy Indolylacetates and Diindolylacetates, Synlett, pp. 1443-1444, May 2001.

著書

• Koichi MIKAMI, Kohsuke AIKAWA. Asymmetric Activation and Deactivation (New Frontier in Asymmetric Catalsis; Mikami, K., Lautens, M., Eds.; WILEY: Hoboken, New Jersey), New Frontiers in Asymmetric Catalysis, WILEY, pp. 221-257, Dec. 2007.
• Koichi MIKAMI, Kohsuke AIKAWA. Asymmetric Ene-Reactions and Cycloadditions (Catalytic Asymmetric Synthesis, Third Edition; Ojima, I., Ed.; WILEY: Hoboken, New Jersey), New Frontiers in Asymmetric Catalysis, WILEY, pp. 683-737, Jan. 2010.

国際会議発表 (査読有り)

• K Mikami, S Kataoka, Y Yusa, K.Aikawa. Racemic but Tropos(Chirally Flexible)BIPHEP Ligands for Rh(Ⅰ)-Complexes:highly Enantioselective Ene-Type Cyclization of 1,6-Enynes, Org. Lett., Vol. 6, No. 21, pp. 3699-3701, 2004.

国際会議発表 (査読なし・不明)

• Ai Kohata, Taiichi Kageyama, Honoka Watanabe, Kohsuke Aikawa, Kunihiko Morihiro, Akimitsu Okamoto, Takashi Okazoe. Fluorinated DNAs with the Enhanced Cell Permeability, The 49th International Symposium on Nucleic Acids Chemistry (ISNAC) 2022, Nov. 2022.

国内会議発表 (査読なし・不明)

• 木幡 愛, 成田美菜子, 影山泰一, 渡邉ほの香, 相川光介, 森廣邦彦, 岡本晃充, 岡添 隆. フッ素化リガンド修飾DNAの細胞内送達, 第46回フッ素化学討論会, Oct. 2023.
• 木幡 愛, 成田美菜子, 影山泰一, 渡邉ほの香, 相川光介, 森廣邦彦, 岡本晃充, 岡添隆. フッ素化リガンド修飾DNAの細胞内送達, 第33回バイオ・高分子シンポジウム, July 2023.
• 門田晃司, 三上峻輝, 木幡愛, 相川光介, 森本淳平, 山東信介, 岡添隆. ペルフルオロアルキル基の細胞膜透過性ペプチド（CPP）への効果, 第45回フッ素化学討論会, Nov. 2022.
• 木幡愛, 影山泰一, 渡邉ほの香, 相川光介, 森廣邦彦, 岡本晃充, 岡添隆. 核酸の細胞内送達を可能にする含フッ素修飾剤, 第45回フッ素化学討論会, Nov. 2022.
• 門田晃司, 三上峻輝, 木幡愛, 相川光介, 森本淳平, 山東信介, 岡添隆. 高度にフッ素化された官能基を持つ細胞膜透過性ペプチド（CPP）, 第59回ペプチド討論会, Oct. 2022.

その他の論文・著書など

• Koichi Mikami, Kohsuke Aikawa, Yukinori Yusa, Jonathan J. Jodry, Masahiro Yamanaka. Tropos or Atropos ? That is the Question !, Synlett, No. 10, pp. 1561-1578, Oct. 2002.
• 相川光介. 含トリフルオロメチル化合物の実用的合成法の開発, 化学と工業 “飛翔する若手科学者”の欄, Vol. 66, No. 7, pp. 565-567, July 2013.
• 相川光介, 三上幸一. 動的キラルな配位子を活用した不斉触媒反応の開発, 有機合成化学協会誌, Vol. 70, No. 12, pp. 45-58, Dec. 2012.
• Kohsuke Aikawa, Koichi Mikami. Asymmetric Catalysis based on Tropos Ligands, Chem. Commun., Vol. 48, No. 90, pp. 11050-11069, Nov. 2012.
• 三上幸一, 小島雅史, 相川光介. Chirality資源としてのラセミ体, 化学工業, Vol. 61, No. 11, pp. 855-860, Nov. 2011.

特許など

• 三上幸一, 遠藤優, 相川光介. ビス（ジフルオロメチル）亜鉛反応剤. 特許. 公開. 国立大学法人東京工業大学, 日本曹達株式会社. 2017/08/17. 特願2017-157451. 2019/03/07. 特開2019-034903. 2019.
• 三上幸一, 石井洸毅, 相川光介. ジフルオロメチル亜鉛化合物. 特許. 登録. 国立大学法人東京工業大学, 東ソー・ファインケム株式会社. 2015/03/23. 特願2015-059500. 2016/10/13. 特開2016-179945. 特許第6556476号. 2019/07/19 2019.
• 三上幸一, 中村雄三, 根岸千幸, 相川光介. ジフルオロシクロプロパン化合物類の製造方法. 特許. 登録. 国立大学法人東京工業大学, 東ソー・エフテック株式会社. 2013/09/26. 特願2013-199096. 2015/04/09. 特開2015-063491. 特許第6133741号. 2017/04/28 2017.
• 三上幸一, 中村雄三, 根岸千幸, 相川光介. ビス（トリフルオロメチル）亜鉛・ＤＭＰＵ錯体、その製造方法並びにそれを用いたトリフルオロメチル基含有化合物の製造方法. 特許. 登録. 国立大学法人東京工業大学. 2013/08/30. 特願2013-180007. 2015/03/16. 特開2015-048322. 特許第6249472号. 2017/12/01 2017.
• 三上幸一, 芹澤宏希, 張媛, 根岸千幸, 相川光介. トリフルオロメチル銅の製造方法. 特許. 公開. 国立大学法人東京工業大学, セントラル硝子株式会社. 2013/03/07. 特願2013-044939. 2014/09/22. 特開2014-172831. 2014.
• 三上幸一, 中村雄三, 根岸千幸, 相川光介. トリフルオロメチル化剤粉末、その製造方法並びにそれを用いたトリフルオロメチル基含有化合物の製造方法. 特許. 登録. 国立大学法人東京工業大学, 東ソー・エフテック株式会社. 2013/02/22. 特願2013-032699. 2014/09/08. 特開2014-162732. 特許第5889817号. 2016/02/26 2016.
• 三上幸一, 中村雄三, 相川光介. トリフルオロメチル化剤、その製造方法並びにそれを用いたトリフルオロメチル基含有化合物の製造方法. 特許. 登録. 国立大学法人東京工業大学, 東ソー・エフテック株式会社. 2012/05/18. 特願2012-113898. 2013/12/05. 特開2013-241345. 特許第5941338号. 2016/05/27 2016.
• 三上幸一, 相川光介, 日置　優太. 光学活性含フッ素オキテセンの製造方法. 特許. 登録. 国立大学法人東京工業大学, セントラル硝子株式会社. 2010/11/26. 特願2010-263128. 2012/06/14. 特開2012-111721. 特許第5669534号. 2014/12/26 2014.
• 三上幸一, 相川光介, 日置　優太. 光学活性芳香族複素５員環置換ヒドロキシ酢酸エステルの製造方法. 特許. 登録. 国立大学法人東京工業大学, セントラル硝子株式会社. 2010/02/15. 特願2010-030659. 2011/08/25. 特開2011-162526. 特許第5570840号. 2014/07/04 2014.
• 三上幸一, 相川光介, 会田　淳平, 石井　章央, 加藤　美杉, 増田　隆司. 光学活性含フッ素オキセタンの製造方法. 特許. 公開. 国立大学法人東京工業大学, セントラル硝子株式会社. 2010/02/19. 特願2010-034169. 2010/10/07. 特開2010-222345. 2010.
• 三上幸一, 相川光介, 宮崎　仁孝. BIPHEP誘導体を配位子とする光学活性遷移金属錯体. 特許. 登録. 国立大学法人東京工業大学, セントラル硝子株式会社. 2009/03/11. 特願2009-058064. 2010/09/24. 特開2010-209013. 特許第5501636号. 2014/03/20 2014.
• 三上幸一, 相川光介, 三村　俊介. 不斉カルボニルーエン反応による光学活性コンボルタミジン誘導体の製造方法. 特許. 公開. 国立大学法人東京工業大学, セントラル硝子株式会社. 2009/03/09. 特願2009-055361. 2010/09/24. 特開2010-208975. 2010.
• 三上幸一, 相川光介, 日置　優太. 光学活性含フッ素アルキニル化生成物の製造方法. 特許. 登録. 国立大学法人東京工業大学, セントラル硝子株式会社. 2009/02/26. 特願2009-044683. 2010/09/09. 特開2010-195736. 特許第5303311号. 2013/06/28 2013.
• 三上幸一, 相川光介, 三村　俊介. 光学活性コンボルタミジン誘導体の製造方法. 特許. 公開. 国立大学法人東京工業大学, セントラル硝子株式会社. 2009/02/26. 特願2009-044685. 2010/09/09. 特開2010-195737. 2010.
• 三上幸一, 相川光介, 石井　章央, 茂木　香織, 大塚　隆史. 光学活性含フッ素カルボニル－エン生成物の製造方法. 特許. 登録. 国立大学法人東京工業大学, セントラル硝子株式会社. 2007/04/17. 特願2007-108681. 2008/10/09. 特開2008-239593. 特許第5090773号. 2012/09/21 2012.
• 三上幸一, 相川光介, 石井　章央, 茂木　香織, 大塚　隆史. 光学活性含フッ素カルボニル－エン生成物の製造方法. 特許. 公開. 国立大学法人東京工業大学, セントラル硝子株式会社. 2007/04/17. 特願2007-108681. 2008/10/09. 特開2008-239593. 2008.

学位論文

• Asymmetric Activation of Racemic Catalysts Bearing Chirally Flexible Ligands,  本文,  Doctor of Engineering,  Tokyo Institute of Technology,  2005/03/--, 

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