論文

• Riku Shinohara, Narihito Ogawa, Hidehisa Kawashima, Kyohei Wada, Shun Saito, Takashi Yamazaki, Yuichi Kobayashi. SN2 Reaction of Diarylmethyl Anions at Secondary Alkyl and Cycloalkyl Carbons, Eur. J. Org. Chem., 2019.
• Shun Saito, Takashi Yamazaki, Yuichi Kobayashi. Stereoselective ozonolysis of TMS-substituted allylic alcohol derivatives and synthesis of 14R,15S- and 14S,15S-diHETE, Organic & Biomolecular Chemistry, Vol. 16, No. 41, pp. 7636–7647, Oct. 2018.
• S. Hiraoka, J. Sakamoto, Kitazume, T., TAKASHI YAMAZAKI. Mesyloxy-Group Migration as the Stereoselective Preparation Method of Various Functionalized Olefins and Its Reaction Mechanism, Org. Lett., Vol. 3, No. 5, pp. 743-746, 2001.
• Y. Kobayashi, G. Biju Kumar, T. Kurachi, H. P. Acharya, T. Kitazume, TAKASHI YAMAZAKI. Furan Ring Oxidation Strategy for the Synthesis of Macrosphelides A and B, J. Org. Chem., Vol. 66, No. 6, pp. 2011-2018, 2001.
• T. Ichige, S. Takei, S. Kawashita, T. Kitazume, T. Kubota, TAKASHI YAMAZAKI. Effect of Allylic CH_3-nF_n Groups (n=1~3) on the π-Facial Diastereoselection, Org. Lett., Vol. 3, No. 18, pp. 2915-2918, 2001.
• V. A. Soloshonok, C.-Z. Cai, V. J. Hruby, L. V. Meervelt, TAKASHI YAMAZAKI. Rational Design of Highly Diastereoselective, Organic Base-Catalyzed, Room-Temperature Michael Addition Reactions, J. Org. Chem, Vol. 65, No. 20, pp. 6688-6696, 2000.
• Shuichi Hiraoka, Johei Sakamoto, Tomoya Kitazume, TAKASHI YAMAZAKI. Computational Interpretations on 5-Endo-trig Cyclization of Terminally Difluorinated Homoallylic Alkoxides, J. Fluorine Chem., Vol. 101, No. 2, pp. 309-313, 2000.
• Shuichi Hiraoka, Johei Sakamoto, Tomoya Kitazume, TAKASHI YAMAZAKI. Anionic 5-Endo-trig Cyclization of Terminally Difluorinated Homoallylic Alkoxides, J. Phys. Chem. A, Vol. 103, No. 34, pp. 6820-6824, 1999.
• T. Sakamoto, K. Takahashi, T. Kitazume, TAKASHI YAMAZAKI. Highly Stereocontrolled Synthesis of Trifluoromethylated Materials with Allylzincs and Allenylzincs Generated by Umpolung of Palladium Complexes, J. Org. Chem., Vol. 64, No. 26, pp. 9467-9474, 1999.
• N. Shinohara, T. Kitazume, S. Sato, TAKASHI YAMAZAKI. Michael Addition of Organocopper Species to 3-[(E)-4,4,4-Trifluorobut-2-enoyl]oxazolidin-2-ones, J. Fluorine Chem., Vol. 97, No. 1-2, pp. 91-96, 1999.
• Hideki Umetani, Tomoya Kitazume, TAKASHI YAMAZAKI. CuCN and Trimethylsilyl Chloride-Catalyzed Regiospecific Grignard Reactions to CF₃-Containing Allylic Derivatives, Isr. J. Chem., Vol. 39, No. 2, pp. 193-205, 1999.
• Makoto Ando, Tomoya Kitazume, Toshio Kubota, Masao Omura, TAKASHI YAMAZAKI. Conformational Fixation of Enolates by Intramolecular Metal…Fluorine Interaction, Org. Lett., Vol. 1, No. 6, pp. 905-908, 1999.
• Shuichi Hiraoka, Tomoya Kitazume, TAKASHI YAMAZAKI. Stereoselective Hydrogenation of D-Glucose-derived Endo-olefins with a CF₃ Group-Experimental and Theoretical Explanations-, Heterocycles, Vol. 47, No. 1, pp. 129-132, 1998.
• Shuichi Hiraoka, Tomoya Kitazume, TAKASHI YAMAZAKI. Highly Stereoselective Route to Aldol Products Incorporating Fluorine-Containing Methyl Groups Starting from a Single D-Glucose-Derived Intermediate, Tetrahedron : Asymmetry, Vol. 8, No. 8, pp. 1157-1160, 1997.
• Shoji Watanabe, Tsutomu Fujita, Masami Sakamoto, Hiroyuki Hamano, Tomoya Kitazume, TAKASHI YAMAZAKI. A Convenient Preparative Method for α-Trifluoromethyl Amines, J. Fluorine Chem., Vol. 83, No. 1, pp. 15-19, 1997.
• Ling Xiao, Tomoya Kitazume, Tetsuo Yonezawa, Yoshitake Sakamoto, Kouji Nogawa, TAKASHI YAMAZAKI. Study for the Determination of the Absolute Configuration of Fluoromethylated Secondary Alcohols by the Modified Mosher Method, J. Fluorine Chem., Vol. 84, No. 1, pp. 19-23, 1997.
• Shuichi Hiraoka, Tomoya Kitazume, TAKASHI YAMAZAKI. Highly Regio-and Stereoselective Alkyl Substitution with Copper Reagents for the Construction of Chiral Trifluoromethylated Quaternary Carbon Centers, Chem. Commun., pp. 1497-1498, 1997.
• Keizo Itoh, Tatsushi Ishizuka, Mitsunori Takeda, Masaaki Namekawa, Tomoya Kitazume, TAKASHI YAMAZAKI. Novel Antiferroelectric Liquid Crystals Derived from Trifluoromethylated Pyranoses, Mol. Cryst. Liq. Cryst., Vol. 302, pp. 277-288, 1997.
• Hideki Umetani, Tomoya Kitazume, TAKASHI YAMAZAKI. Highly Stereoselective SN₂' Reactions of Grignard Reagents Towards CF₃-Containing Allylic Acetates, Tetrahedron Lett., Vol. 38, No. 38, pp. 6705-6708, 1997.
• Shoji Watanabe, Tsutomu Fujita, Masami Sakamoto, Hiromichi Takeda, Tomoya Kitazume, TAKASHI YAMAZAKI. A Convenient Method for the Preparation of α, α-Difluoro-β-ketoesters and α, α-Difluoro-amides from Terpenic and Perfumery Aldehydes, J. Fluorine Chem., Vol. 82, No. 1, pp. 1-7, 1997.
• Shuichi Hiraoka, Tomoya Kitazume, TAKASHI YAMAZAKI. Highly Stereoselective Introduction of Fluorine-Containing Methyl Groups at 2 Position of D-Glucose, Synlett, No. 6, pp. 669-670, 1997.
• Tomoya Kitazume, TAKASHI YAMAZAKI. Interaction of Fluorine with Proton or Metals, J. Synth. Org. Chem. Jpn., Vol. 54, No. 8, pp. 665-674, 1996.
• TAKASHI YAMAZAKI. Stereoselective Introduction of a Trifluoromethyl Group into 1,5-Dicarbonyl Compounds via Michael Addition Reaction, Rev. Heteroatom Chem., Vol. 14, pp. 165-182, 1996.
• Tsutomu Konno, Tomoya Kitazume, TAKASHI YAMAZAKI. Synthesis and Application of α-Trifluoromethylated Aldehydes, Tetrahedron, Vol. 52, No. 1, pp. 199-208, 1996.
• Takayuki Oniki, Tomoya Kitazume, TAKASHI YAMAZAKI. 1,2-and 1,3-O,O-Silyl Migration Reactions of Fluorine-Containing Monosilylated Diols, Tetrahedron, Vol. 52, No. 36, pp. 11753-11762, 1996.
• TAKASHI YAMAZAKI. Modified Preparation Method of Trifluoromethylated Propargylic Alcohols and Its Application to Chiral 2,6-Dideoxy-6,6,6-Trifluorosugars, J.Org.Chem., Vol. 60, No. 19, pp. 6046, 1995.
• M. Takeda, T. Kitazume, M. Koden, TAKASHI YAMAZAKI. Synthesis and Properties of Trifluoromethylated Chiral for Ferroelectric Liquid Crystals, J.Mat.Sci., Vol. 30, pp. 5199-5209, 1995.
• TAKASHI YAMAZAKI. Highly Diastereoselective Sequential Enolate-Michael Addition-Ireland Claisen Rearrangement, J.Org.Chem., Vol. 60, No. 25, pp. 8140-8141, 1995.
• TAKASHI YAMAZAKI. Stereoselective Synthesis of Trifluoromethylated Compounds with Controlled Adjacent Tertiary Carbons by Michael Addition to (E)-3-(Trifluoromethyl)Acrylates, J.Org.Chem., Vol. 60, No. 14, pp. 4363, 1995.
• TAKASHI YAMAZAKI. Preparation and Biological Evaluation of β-Trifluoromethyl-α,β-Unsaturated Carbonyl Compounds, Bioorg .Med.Chem.Lett., Vol. 5, No. 9, pp. 923, 1995.
• TAKASHI YAMAZAKI. New Ferroelectric Liquid Crystals form Trifluoromethylated Pyranoses Showing Very Large Spontaneous Polarization, Chem.Lett, No. 8, pp. 641, 1995.
• TAKASHI YAMAZAKI. Novel Steroselective Synthesis of Chiral 2, 6-Dideoxy-6, 6, 6-trifluoro Sugars via Enzymatic Resolution of Trifluoromethylated Propynylic Alcohol, ┣DBJ. Chem. Soc, Chem. Commun(/)-┫DB., No. 1, pp. 51, 1995.
• TAKASHI YAMAZAKI. Molecular Orbital Calculations in the Field of Fluorine Chemistry, ┣DBThe Chemical Times(/)-┫DB, No. 4, pp. 2, 1994.
• TAKASHI YAMAZAKI. Preparation of 6-Deoxy-6, 6, 6-trifluoro-D-mannose and D-Allose from Enzymatically Resolved 2-Butenolides, ┣DBTetrahedron : Asym(/)-┫DB., Vol. 4, pp. 1059, 1994.
• TAKASHI YAMAZAKI. Synthesis and Properties of Pyranose Derivatives with Trifluoromethyl Group Used as Chiral Dopants for Ferroelectric Liquid Crystals, ┣DBChem. Lett(/)-┫DB., pp. 839, 1994.
• TAKASHI YAMAZAKI. Reaction of Trifluoroacetaldehyde with Some Bromoesters, ┣DBJ. Fluorine Chem(/)-┫DB., Vol. 68, pp. 59, 1994.
• TAKASHI YAMAZAKI. Synthesis of Optically Active γ-Lactones and Dopants for Ferroelectric Liquid Crystals Possessing a Trifluoromethyl Group, ┣DBJ. Fluorine Chem(/)-┫DB., Vol. 67, pp. 149, 1994.
• TAKASHI YAMAZAKI. Ready Carbon-Carbon Bond Formation of 2- (Trifluoromethyl) acrylate via Michael Addition Reactions, ┣DBJ. Org. Chem(/)-┫DB., Vol. 59, pp. 5100, 1994.
• TAKASHI YAMAZAKI. Stereoselective Preparation of Optically Active 6-Deoxy-6, 6, 6-trifluorohexopyranoses, ┣DBJ. Synth. Org. Chem. Jpn(/)-┫DB., Vol. 52, No. 9, pp. 734, 1994.
• TAKASHI YAMAZAKI. Diastereospecific Cyclization of Optically Active Trifluoromethylated Epoxycarbamates, ┣DBTetrahedron : Asym(/)-┫DB., Vol. 5, No. 9, pp. 1823, 1994.
• TAKASHI YAMAZAKI. A Highly Sterocontrolled Synthetic Approach to 1, 6-Dideoxy-6, 6-difluoroazasugar Derivatives, ┣DBTetrahedron : Asym(/)-┫DB., Vol. 5, pp. 1029, 1994.
• TAKASHI YAMAZAKI. Trifluoromethylated Pyranose Derivatives as the Chiral Dopant for Ferroelectric Liquid Crystals, ┣DBFerroelectrics(/)-┫DB, Vol. 148, pp. 85, 1993.
• TAKASHI YAMAZAKI. Development of a Novel Pathway to Access 6-Deoxy-6, 6, 6-trifluorosugars via 1, 2-Migration of a ┣DBtert(/)-┫DB-Butyldimethylsilyl Group, ┣DBJ. Org. Chem(/)-┫DB., Vol. 58, pp. 4346, 1993.
• TAKASHI YAMAZAKI. A Convenient Synthesis of Trifluoromethylated Ferroelectric Liquid Crystals, ┣DBJ. Fluorine Chem(/)-┫DB., Vol. 60, pp. 135, 1993.
• TAKASHI YAMAZAKI. A Remarkably Simple Route to Versatile Difluoromethylated Molecules, ┣DBJ. Fluorine Chem(/)-┫DB., Vol. 58, pp. 2302, 1993.
• TAKASHI YAMAZAKI. Chiral Trifluoromethylated 2-Butenolides for the Construction of 6-Deoxy-6,6,6-trifluorosugars, J. Chem. Soc. , Chem. Commun., No. 1, pp. 55, 1992.
• TAKASHI YAMAZAKI. Stereoselective Micheal Addition Reactions of Acylated Oxazolidinones to Ethyl 3-Trifluoromethyl acrylate, Chem. Lett., No. 12, pp. 2175, 1991.
• TAKASHI YAMAZAKI. An Optimized Synthesis of (2S, 5S)-2,5-Dimethylpyrrolidine, Synlett, No. 8, pp. 573, 1991.
• TAKASHI YAMAZAKI. The Enantioselective Fluoroacetamide Acetal Claisen Rearrangements of N-Fluoroacetyl-trans-(2R, 5R)-2,5-dimethylpyrrolidine, Tetrahedron Lett., Vol. 32, No. 34, pp. 4267, 1991.
• TAKASHI YAMAZAKI. Highly Diastereoselective Michael Addition Reactions of Lithium Enolates to Ethyl 3-Trifluoromethylacrylate, Chem. Lett., No. 12, pp. 2171, 1991.
• TAKASHI YAMAZAKI. Preparation and Evaluation of Optically Active 4,4-Difluorothreonine as a Potent Novel Antitumor Material, BioMed. Chem. Lett., Vol. 1, No. 5, pp. 271, 1991.
• 山崎孝. トリフルオロメチル基を有する化合物の立体選択的構築, 有機合成化学協会誌, Vol. 49, No. 8, pp. 721, 1991.
• 山崎孝. 酵素による加水分解をカギ反応とする光学活性含フッ素化合物の合成, 化学と工業, Vol. 43, No. 2, pp. 206, 1990.

著書

• S. Hiraoka, T. Kitazume, TAKASHI YAMAZAKI. Diastereoselective Construction of Novel Sugars Containing Variously Fluorinated Methyl Groups As Intermediates for Fluorinated Aldols, Asymmetric Fluoroorganic Chemistry: Synthesis, Applications, and Future Directions (ACS Symposium Series), Asymmetric Fluoroorganic Chemistry: Synthesis, Applications, and Future Directions (ACS Symposium Series), Vol. 746, pp. 142-156, 2000.
• TAKASHI YAMAZAKI. Asymmetric Michael Addition Reactions of Fluorocarbons; Enantiocontrolled Synthesis of Fluoro-Organic Compounds, Enantiocontrolled Synthesis of Fluoro-Organic Compounds (John Wiley & Sons), Enantiocontrolled Synthesis of Fluoro-Organic Compounds (John Wiley & Sons), pp. 263-286, 1999.
• Tomoya Kitazume, TAKASHI YAMAZAKI. Coordination Ability of Fluorine to Proton or Metals Based on Experimental and Theoretical Evidence, Enantiocontrolled Synthesis of Fluoro-Organic Compounds (John Wiley & Sons), Enantiocontrolled Synthesis of Fluoro-Organic Compounds (John Wiley & Sons), pp. 575-600, 1999.
• Tomoya Kitazume, TAKASHI YAMAZAKI. Experimental Methods in Organic Fluorine Chemistry, Kodansha, Kodansha, 1998.
• Kenji Mizutani, Tomoya Kitazume, TAKASHI YAMAZAKI. Efficient Synthetic Routes to Chiral 6-Deoxy-6,6,6-trifluorosugars via Intramolecular 1,2-O,O-Silyl Migration, Biomedical Frontiers of Fluorine Chemistry(Ojima, I. , McCarthy, J. R. , Welch, J. T. , Eds, ; ACS : Washington, D. C. ), Biomedical Frontiers of Fluorine Chemistry(Ojima, I. , McCarthy, J. R. , Welch, J. T. , Eds, ; ACS : Washington, D. C. ), Vol. 639, pp. 105-116, 1996.
• TAKASHI YAMAZAKI. The Fluoroacetamide Acetal Claisen Rearrangement as a Tool for Asymmetric Synthesis(Synthetic Fluorine Chemistry, chapter 15), John Wiley & Sons, John Wiley & Sons, 1992.
• TAKASHI YAMAZAKI. Effect of the Fluorine Atom on Stereocontrolled Synthesis-Chemical or Microbial Methods, Selective Fluorination(Welch, J. T., Ed. ; ACS : Washington, D. C. ), Selective Fluorination(Welch, J. T., Ed. ; ACS : Washington, D. C. ), Vol. 456, pp. 175, 1991.

学位論文

• ケイ素または硫黄官能基を持つ含トリフルオロメチル合成ブロックの研究,  本文,  Doctor of Engineering,  東京工業大学,  1986/--/--, 

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